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烯丙基溴

烯丙基溴用途

【用途一】
用作医药中间体
【用途二】
用于有机合成如合成染料、香料；医药工业上用于西可巴比妥的制造；农业上用作土壤熏蒸剂。
【用途三】
本品用于有机合成，可用合成染料、香料；医药工业用于制“西可巴比妥”药物；农业用作土壤熏蒸剂。

烯丙基溴名称

[ CAS 号 ]:
106-95-6

[ 中文名 ]:
3-溴丙烯

[ 英文名 ]:
allyl bromide

[中文别名 ]:

[英文别名 ]:

3-Bromo-1-propene
1-bromo-2-propene
bromo-3propene
prop-2-enyl bromide
Allylbromid
3-bromo-propen
allylic bromide
allylbromide
CH2=CHCH2Br
Bromoallylene

烯丙基溴物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
68.1±9.0 °C at 760 mmHg

[ 熔点 ]:
-119 °C

[ 分子式 ]:
C₃H₅Br

[ 分子量 ]:
120.976

[ 闪点 ]:
-2.2±0.0 °C

[ 精确质量 ]:
119.957458

[ LogP ]:
1.79

[ 外观性状 ]:
透明至淡黄色液体

[ 蒸汽密度 ]:
4.2 (vs air)

[ 蒸汽压 ]:
153.5±0.1 mmHg at 25°C

[ 折射率 ]:
1.455

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

[ 稳定性 ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
insoluble

烯丙基溴MSDS

烯丙基溴毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC7090000

CHEMICAL NAME :: Propene, 3-bromo-

CAS REGISTRY NUMBER :: 106-95-6

BEILSTEIN REFERENCE NO. :: 0605308

LAST UPDATED :: 199712

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C3-H5-Br

MOLECULAR WEIGHT :: 120.99

WISWESSER LINE NOTATION :: E2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 120 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 gm/m3/30M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 48 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 4110 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Human HeLa cell

DOSE/DURATION :: 500 umol/L

REFERENCE :: CALEDQ Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975- Volume(issue)/page/year: 20,263,1983

烯丙基溴安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H301-H314-H340-H350-H400

[ 警示性声明 ]:
P201-P210-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable

[ 风险声明 (欧洲) ]:
R11;R23/25;R34;R50

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S60-S61

[ 危险品运输编码 ]:
UN 1099 3/PG 1

[ WGK德国 ]:
2

[ RTECS号 ]:
UC7090000

[ 包装等级 ]:
I

[ 危险类别 ]:
3

[ 海关编码 ]:
2942000000

烯丙基溴合成路线

烯丙基溴上下游产品

烯丙基溴上游产品

烯丙基溴下游产品

烯丙基溴制备

1.由烯丙醇溴化而得：向反应罐投入氢溴酸，在搅拌下加入硫酸、烯丙醇。升温回流2h，加热至8℃时有馏液蒸出，收集68-73℃馏分。水洗后，用无水硫酸钠脱水，过滤，得烯丙基溴。

2.制法：

于装有搅拌器、滴液漏斗、蒸馏装置的反应瓶中，加入250g(48%)的氢溴酸，慢慢加入75g浓硫酸，再加入烯丙醇58g(1.0mol)。搅拌下，滴加浓硫酸75g，加热反应瓶，滴加硫酸的同时，蒸出生成的烯丙基溴，约30min反应完。馏出液依次用5%的碳酸钠、水洗涤、无水氯化钙干燥，分馏，收集69～72℃的馏分，得烯丙基溴(1)112g,收率93%。

烯丙基溴海关

[ 海关编码 ]: 2903399090

[ 中文概述 ]:
2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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J. Pharm. Pharmacol. 66(9) , 1271-81, (2014)

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