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嘧菌胺

嘧菌胺用途

本品属嘧啶胺类杀菌剂、以0.l～1.0kg/ha施用,对苹果和梨的上的黑星病茵，黄瓜、葡萄、草每和番茄上灰葡萄孢菌有防效。

嘧菌胺名称

[ CAS 号 ]:
110235-47-7

[ 中文名 ]:
嘧菌胺

[ 英文名 ]:
4-METHYL-N-PHENYL-6-(PROP-1-YNYL)PYRIMIDIN-2-AMINE

[中文别名 ]:

[英文别名 ]:

4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine
N-(4-methyl-6-prop-1-ynylpyrimidin-2-yl)aniline
Mepanipyrim
4-methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine
MFCD01656050
EINECS 432-140-7

嘧菌胺物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
418.2±47.0 °C at 760 mmHg

[ 熔点 ]:
132.8ºC

[ 分子式 ]:
C₁₄H₁₃N₃

[ 分子量 ]:
223.273

[ 闪点 ]:
206.7±29.3 °C

[ 精确质量 ]:
223.110947

[ PSA ]:
37.81000

[ LogP ]:
3.28

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.618

嘧菌胺MSDS

嘧菌胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UV6261540

CHEMICAL NAME :: 2-Pyrimidinamine, 4-methyl-N-phenyl-6-(1-propynyl)-

CAS REGISTRY NUMBER :: 110235-47-7

LAST UPDATED :: 199204

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C14-H13-N3

MOLECULAR WEIGHT :: 223.30

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,546,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,546,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,546,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >2250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,546,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: >2250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,546,1991

嘧菌胺安全信息

[ 符号 ]:

GHS08, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351-H410

[ 警示性声明 ]:
P273-P281-P501

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R51/53

[ 安全声明 (欧洲) ]:
S60

[ 危险品运输编码 ]:
UN 3077

[ RTECS号 ]:
UV6261540

[ 海关编码 ]:
2933599014

嘧菌胺合成路线

嘧菌胺上下游产品

嘧菌胺上游产品

嘧菌胺下游产品

嘧菌胺制备

以苯胺为原料经一系列反应制得。

嘧菌胺海关

[ 海关编码 ]: 2933599014

[ 中文概述 ]:
2933599014 嘧草醚,双草醚,除草啶,环草啶等〔包括异草啶,异丙酯草醚,嘧草硫醚,特草啶〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2933599014 6-nitroso-7h-purine。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

嘧菌胺文献

Gas chromatographic determination of azoxystrobin, fluazinam, kresoxim-methyl, mepanipyrim, and tetraconazole in grapes, must, and wine.

J. AOAC Int. 81(6) , 1185-9, (1998)

Azoxystrobin, fluazinam, kresoxim-methyl, mepanipyrim, and tetraconazole were determined in grapes, must, and wine by a gas chromatographic method with nitrogen-phosphorus (NP) and mass spectrometric ...

Evaluation of anilinopyrimidine and other fungicides for control of grey mould (Botrytis cinerea) in container-grown Calluna vulgaris.

Pest Manag. Sci. 64(7) , 748-54, (2008)

Grey mould (Botrytis cinerea Pers. ex Fr.) is a damaging disease affecting container-grown Calluna vulgaris (L.) Hull. Trials were conducted to test anilinopyrimidine fungicides (pyrimethanil, cyprodi...

[Determination of fungicide anilinopyrimidine residues in food by series solid phase extraction-high performance liquid chromatography-tandem mass spectrometry].

Se Pu 30(9) , 896-902, (2012)

A high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/ MS) method was established for the determination of fungicide anilinopyrimidine residues including pyrimethanil, mepanipyrim...

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嘧菌胺