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1-溴代正己烷

1-溴代正己烷用途

【用途一】
用作溶剂，也用于有机合成
【用途二】
溴己烷（111-25-1）是用于制备聚酮的离子液体的原料药

1-溴代正己烷名称

[ CAS 号 ]:
111-25-1

[ 中文名 ]:
溴已烷

[ 英文名 ]:
1-Bromohexane

[中文别名 ]:

[英文别名 ]:

1-bromo-hexan
HEXYL BROMIDE, N-
1-BROMO HEXANE
1-hexylbromide
HEXYLBROMIDE
HEXANE,1-BROMO-
EINECS 203-850-2
n-hexyl bromide
HEXYL BROMIDE
1-BROMO HEPTANE

1-溴代正己烷物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
154.9±3.0 °C at 760 mmHg

[ 熔点 ]:
−85 °C(lit.)

[ 分子式 ]:
C₆H₁₃Br

[ 分子量 ]:
165.071

[ 闪点 ]:
57.2±0.0 °C

[ 精确质量 ]:
164.020050

[ LogP ]:
3.81

[ 外观性状 ]:
透明或浅黄色液体

[ 蒸汽密度 ]:
5.7 (vs air)

[ 蒸汽压 ]:
4.0±0.3 mmHg at 25°C

[ 折射率 ]:
1.447

[ 储存条件 ]:
包装完整、轻装轻放,库房通风、远离明火、高温、与氧化剂、强酸分开存放

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.

[ 水溶解性 ]:
水溶性：不溶；可溶于：醇,氯仿,丙酮,乙醚

1-溴代正己烷MSDS

1-溴代正己烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO0925000

CHEMICAL NAME :: Hexane, 1-bromo-

CAS REGISTRY NUMBER :: 111-25-1

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C6-H13-Br

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 550 gm/m3/30M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FAVUAI Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. (Izdatel'stvo Naukova Dumka, Kiev, USSR) No.1- 1966- Volume(issue)/page/year: 7,35,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1226 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 13600 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(4),55,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993

1-溴代正己烷安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R10;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S16

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
MO0925000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
29033036

1-溴代正己烷合成路线

1-溴代正己烷上下游产品

1-溴代正己烷上游产品

1-溴代正己烷下游产品

1-溴代正己烷制备

将16g(0.1mol)溴溶解在50mL四氯化碳中，搅拌下缓慢逐渐滴加至13g(0.1mol)庚酸和22g(0.0945m化汞与150mL干燥四氯化碳的溶液中。混合物回流滤液用5%NaOH溶液洗涤，再用水洗涤，用无水硫夜。分馏得6g(36%)1-溴己烷,。

1-溴代正己烷海关

[ 海关编码 ]: 2903399090

[ 中文概述 ]:
2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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