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2-甲氧基丙烯

2-甲氧基丙烯用途

用途一：用作医药中间体
用途二：2-甲氧基丙烯（116-11-0）是合成克拉霉素（Clarithromycin,简称CLM）的中间体。

2-甲氧基丙烯名称

[ CAS 号 ]:
116-11-0

[ 中文名 ]:
2-甲氧基丙烯

[ 英文名 ]:
2-methyoxypropene

[中文别名 ]:

[英文别名 ]:

2-Methoxyprop-1-ene
MFCD00014929
2-methyoxypropene
2-Methoxy-1-propene
Isopropenyl Methyl Ether
EINECS 204-125-3
2-Methoxyprop-1-en
Methyl prop-1-en-2-yl ether
1-Propene, 2-methoxy-

2-甲氧基丙烯物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
32.0±9.0 °C at 760 mmHg

[ 熔点 ]:
< 25ºC

[ 分子式 ]:
C₄H₈O

[ 分子量 ]:
72.106

[ 闪点 ]:
-29.4±0.0 °C

[ 精确质量 ]:
72.057518

[ PSA ]:
9.23000

[ LogP ]:
1.06

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
590.8±0.1 mmHg at 25°C

[ 折射率 ]:
1.374

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
negligible

2-甲氧基丙烯MSDS

2-甲氧基丙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UD0800000

CHEMICAL NAME :: 1-Propene, 2-methoxy-

CAS REGISTRY NUMBER :: 116-11-0

BEILSTEIN REFERENCE NO. :: 1734635

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C4-H8-O

MOLECULAR WEIGHT :: 72.12

WISWESSER LINE NOTATION :: 1YO1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1870 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 64000 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >20 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

2-甲氧基丙烯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H224-H302

[ 补充危害声明 ]:
May form explosive peroxides.

[ 警示性声明 ]:
P210

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F+:Highlyflammable;Xn:Harmful;

[ 风险声明 (欧洲) ]:
R12;R19;R22

[ 安全声明 (欧洲) ]:
S3-S16-S29-S33-S7/9-S9-S18

[ 危险品运输编码 ]:
UN 1993 3/PG 1

[ WGK德国 ]:
1

[ RTECS号 ]:
UD0800000

[ 包装等级 ]:
I

[ 危险类别 ]:
3

[ 海关编码 ]:
2909199090

2-甲氧基丙烯合成路线

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2-甲氧基丙烯海关

[ 海关编码 ]: 2909199090

[ 中文概述 ]:
2909199090. 其他无环醚及其卤化衍生物（包括磺化，硝化或亚硝化衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

2-甲氧基丙烯文献

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Increasing evidence suggests that phospholipid peroxidation plays important roles in the pathogenesis of various diseases, such as atherosclerosis. With regard to the biochemical processes that initia...

E. Fanton et al.

J. Org. Chem. 46 , 4057, (1981)

J. Am. Chem. Soc. 115 , 4429, (1993)

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