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2-(二叔丁基膦)-3,6-二甲氧基-2'-4'-6'三-1-丙基-1,1'-双苯基

用途

有机膦配体

名称

[ CAS 号 ]:
1160861-53-9

[ 中文名 ]:
2-二叔丁基膦-2′,4′,6′-三异丙基-3,6-二甲氧基-1,1′-联苯

[ 英文名 ]:
Di-tert-butyl(2',4',6'-triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine

[中文别名 ]:

[英文别名 ]:

T-BUTYLBRETTPHOS
tert-Butyl BrettPhos
t-BuBrett Phos
tBuBrettPhos
t-BuBrett-Phos
t-BuBrettPhos

物理化学性质

[ 沸点 ]:
534.9±50.0 °C at 760 mmHg

[ 熔点 ]:
171 °C

[ 分子式 ]:
C₃₁H₄₉O₂P

[ 分子量 ]:
484.693

[ 闪点 ]:
347.6±30.4 °C

[ 精确质量 ]:
484.347015

[ PSA ]:
32.05000

[ LogP ]:
10.28

[ 外观性状 ]:
固体;White to Light yellow powder to crystal

[ 蒸汽压 ]:
0.0±1.4 mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免空气

MSDS

安全信息

[ 危害码 (欧洲) ]:
Xi

[ 危险品运输编码 ]:
NONH for all modes of transport

合成路线

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文献

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

更多文献

2-(二叔丁基膦)-3,6-二甲氧基-2'-4'-6'三-1-丙基-1,1'-双苯基

用途

名称

物理化学性质

MSDS

详细MSDS(安全技术说明书)

安全信息

合成路线

详细合成路线

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文献

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