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4-甲基-3-硝基苯胺

4-甲基-3-硝基苯胺用途

【用途一】
用作有机合成中间体

4-甲基-3-硝基苯胺名称

[ CAS 号 ]:
119-32-4

[ 中文名 ]:
4-甲基-3-硝基苯胺

[ 英文名 ]:
3-NITRO-4-TOLUIDINE

[中文别名 ]:

[英文别名 ]:

5-Nitro-4-toluidine
4-Amino-1-methyl-2-nitrobenzene
1-amino-3-nitro-4-methylbenzene
p-Toluidine,3-nitro
3-nitro-4-methylphenylamine
3-NITRO-4-TOLUIDINE
3-Nitro-p-toluidine
MFCD00007910
Benzenamine,4-methyl-3-nitro
2-nitro-4-aminotoluene

4-甲基-3-硝基苯胺物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
306.1±22.0 °C at 760 mmHg

[ 熔点 ]:
74-77 °C(lit.)

[ 分子式 ]:
C₇H₈N₂O₂

[ 分子量 ]:
152.151

[ 闪点 ]:
138.9±22.3 °C

[ 精确质量 ]:
152.058578

[ PSA ]:
71.84000

[ LogP ]:
1.83

[ 外观性状 ]:
橙色粉末

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.616

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类、食品添加剂分开存放

4-甲基-3-硝基苯胺MSDS

详细MSDS(安全技术说明书)

4-甲基-3-硝基苯胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XU8227000

CHEMICAL NAME :: p-Toluidine, 3-nitro-

CAS REGISTRY NUMBER :: 119-32-4

BEILSTEIN REFERENCE NO. :: 0638984

LAST UPDATED :: 199701

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C7-H8-N2-O2

MOLECULAR WEIGHT :: 152.17

WISWESSER LINE NOTATION :: ZR D1 CNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6860 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - wild bird species

DOSE/DURATION :: 3200 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 1 mg/plate

REFERENCE :: SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. (Nippon Sangyo Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160, Japan) V.1- 1959- Volume(issue)/page/year: 29,34,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5462 No. of Facilities: 4 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1251 (estimated)

4-甲基-3-硝基苯胺安全信息

[ 符号 ]:

GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H311-H331-H373-H411

[ 警示性声明 ]:
P261-P273-P280-P301 + P310-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R23/24/25;R33;R51/53

[ 安全声明 (欧洲) ]:
S28-S36/37-S45-S61-S28A

[ 危险品运输编码 ]:
UN 2660 6.1/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
XU8227250

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

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4-甲基-3-硝基苯胺文献

Bioremediation of 2,4-dinitrotoluene (2,4-DNT) in immobilized micro-organism biological filter.

J. Appl. Microbiol. 110(6) , 1476-84, (2011)

To evaluate the biodegradability of 2,4-DNT using an anaerobic filter (AF) combined with a biological aerated filter (BAF), and elucidate the degradation mechanism of 2,4-DNT and analyze the bacterial...

Reductive removal of 2,4-dinitrotoluene and 2,4-dichlorophenol with zero-valent iron-included biochar.

Bioresour. Technol. 216 , 1014-21, (2016)

In order to remediate organic contaminants in natural waters and soils, a novel zero-valent iron [Fe(0)]-included biochar was synthesized via slow pyrolysis. 2,4-Dinitrotoluene (DNT) and 2,4-dichlorop...

Metabolism of 2,4-dinitro[14C]toluene by freshly isolated Fischer-344 rat primary hepatocytes.

Drug Metab. Dispos. 9(1) , 10-4, (1981)

Fischer-344 rat hepatocytes display a capacity for both oxidation and reduction of 2,4-dinitrotoluene (2,4-DNT), a potent hepatocarcinogen. The major metabolite detected by high-pressure liquid chroma...

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