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氢氧化钯

氢氧化钯用途

【用途一】
催化剂，合成多种钯化合物和催化剂的原料。去苄化试剂

氢氧化钯名称

[ CAS 号 ]:
12135-22-7

[ 中文名 ]:
氢氧化钯

[ 英文名 ]:
Pearlmans Catalyst

[中文别名 ]:

[英文别名 ]:

palladium(2+),dihydroxide
Palladium(2+) dihydroxide
Palladium(II) hydroxide
MFCD00064599
PALLADIUM HYDROXIDE
Pearlman's Catalyst
Pearlmans Catalyst
EINECS 235-219-2
Palladium hydroxide on carbon

氢氧化钯物理化学性质

[ 沸点 ]:
100ºC at 760 mmHg

[ 分子式 ]:
H₂O₂Pd

[ 分子量 ]:
140.435

[ 精确质量 ]:
139.908966

[ PSA ]:
46.12000

[ 外观性状 ]:
黑色粉末

[ 蒸汽压 ]:
24.5mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
INSOLUBLE

氢氧化钯MSDS

详细MSDS(安全技术说明书)

氢氧化钯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
F,Xi

[ 风险声明 (欧洲) ]:
11-36/37/38

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
UN1325

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

氢氧化钯制备

30g氯化钯溶于43ml浓盐酸和570ml水中，加入68.6g活性炭，迅速搅拌并加热至60℃。在此混合物中加入31g粒状氢氧化钠，加入的速度以温度不超过80℃为宜。然后在混合物中加入6.6g固体碳酸氢钠，搅拌12h。滤出催化剂，用430ml水洗涤，再用430ml水和8.6ml乙酸的混合液洗涤。滤出催化剂，在65℃真空下干燥。在N2保护下存放。

氢氧化钯文献

Photoinduced intermolecular cross-linking of gas phase triacylglycerol lipid ions.

Eur. J. Mass Spectrom. (Chichester, Eng.) 21 , 287-96, (2015)

Complex mixtures of plant derived triglycerol (TG) lipids are commonly used as feedstock components for the production of industrial polymers. However, there remains a need for the development of anal...

Postsynthetic conjugation of RNA to carboxylate and dicarboxylate molecules.

Nucleosides Nucleotides Nucleic Acids 34 , 753-62, (2015)

Carboxylates and dicarboxylates are important phosphate mimics. Herein, we present a simple synthetic route for the preparation of RNA carboxylate/dicarboxylate conjugates, starting from suitably prot...

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