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双环[3,2,0]庚-2-烯-6-酮

双环[3,2,0]庚-2-烯-6-酮名称

[ CAS 号 ]:
13173-09-6

[ 中文名 ]:
双环[3,2,0]庚-2-烯-6-酮

[ 英文名 ]:
Bicyclo[3.2.0]hept-2-en-6-one

[中文别名 ]:

[英文别名 ]:

MFCD00066201
Bicyclo[3.2.0]hept-2-en-6-one
bicyclo[3.2.0]hept-3-en-7-one

双环[3,2,0]庚-2-烯-6-酮物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
186.6±9.0 °C at 760 mmHg

[ 分子式 ]:
C₇H₈O

[ 分子量 ]:
108.138

[ 闪点 ]:
66.3±13.7 °C

[ 精确质量 ]:
108.057518

[ PSA ]:
17.07000

[ LogP ]:
0.45

[ 蒸汽压 ]:
0.7±0.4 mmHg at 25°C

[ 折射率 ]:
1.546

[ 储存条件 ]:
室温，密封，干燥

双环[3,2,0]庚-2-烯-6-酮MSDS

双环[3,2,0]庚-2-烯-6-酮安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H315-H318-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R37/38;R41

[ 安全声明 (欧洲) ]:
S26-S39

[ 危险品运输编码 ]:
UN1224

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2914299000

双环[3,2,0]庚-2-烯-6-酮合成路线

双环[3,2,0]庚-2-烯-6-酮上下游产品

双环[3,2,0]庚-2-烯-6-酮上游产品

双环[3,2,0]庚-2-烯-6-酮下游产品

双环[3,2,0]庚-2-烯-6-酮海关

[ 海关编码 ]: 2914299000

[ 中文概述 ]:
2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

双环[3,2,0]庚-2-烯-6-酮文献

Asymmetric Baeyer-Villiger oxidation with Co (Salen) and H2O2 in water: striking supramolecular micelles effect on catalysis. Bianchini G, et al.

Green Chem. 11(10) , 1517-1520, (2009)

Synthesis and Characterization of New Chalcone Derivatives from cis-Bicyclo [3.2. 0] hept-2-en-6-one Ceylan M and Findik E.

Synth. Commun. 39(6) , 1049-54, (2009)

Preparative scale Baeyer-Villiger biooxidation at high concentration using recombinant Escherichia coli and in situ substrate feeding and product removal process.

Nat. Protoc. 3(3) , 546-54, (2008)

An efficient biocatalytic process based on the use of adsorbent resin (in situ substrate feeding and product removal) makes experiments at high substrate concentration possible by overcoming limitatio...

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