硫化锑

硫化锑用途

【用途一】
主要用于生产安全火柴、鞭炮、军火和在橡胶工业中作为硬化剂或颜料
【用途二】
用作分析试剂及橡胶硫化剂，也用于焰火和炸药的制备
【用途三】
主要用于制造火柴和烟火，各种锑盐和有色玻璃。橡胶工业用作硫化剂及军工用等。
【用途四】
橡胶硫化剂。焰火、玻璃、炸药、油漆颜料的制造。

硫化锑名称

[ CAS 号 ]:
1345-04-6

[ 中文名 ]:
硫化锑

[ 英文名 ]:
Antimony sulfide

[中文别名 ]:

三硫化二锑

[英文别名 ]:

Antimony sulfide
sulfanylidenestibanylium
MFCD00011217
Antimony(III) sulfide
Stibine, 1,1'-thiobis[1-thioxo-
EINECS 215-713-4
Dithioxodistibathiane
Amtimony sulfide

硫化锑物理化学性质

[ 密度 ]:
4.64 g/mL at 25ºC(lit.)

[ 沸点 ]:
1150ºC

[ 熔点 ]:
550ºC

[ 分子式 ]:
S₃Sb₂

[ 分子量 ]:
339.715

[ 精确质量 ]:
337.723846

[ PSA ]:
89.48000

[ LogP ]:
1.94460

[ 外观性状 ]:
橙色粉末

[ 蒸汽压 ]:
12600mmHg at 25°C

[ 折射率 ]:
4.303

[ 储存条件 ]:
库房通风低温干燥,与酸类,食品分开储运

[ 稳定性 ]:
Stable. Incompatible with acids (reacting to form poisonous hydrogen sulfide), moisture, water.

硫化锑MSDS

详细MSDS(安全技术说明书)

硫化锑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CC9450000

CHEMICAL NAME :: Antimony trisulfide

CAS REGISTRY NUMBER :: 1345-04-6

LAST UPDATED :: 199712

DATA ITEMS CITED :: 38

MOLECULAR FORMULA :: S3-Sb2

MOLECULAR WEIGHT :: 339.68

WISWESSER LINE NOTATION :: SB2 S3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 580 ug/m3/35W

TOXIC EFFECTS :: Cardiac - EKG changes not diagnostic of specified effects Vascular - BP elevation not characterized in autonomic section Gastrointestinal - ulceration or bleeding from stomach

REFERENCE :: IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 23,521,1954

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1390 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 10,15,1941

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 209 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,23,1982

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: >139 mg/kg

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(7),25,1964 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:STEL 0.5 ppm JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4884 No. of Facilities: 786 (estimated) No. of Industries: 34 No. of Occupations: 27 No. of Employees: 26669 (estimated) No. of Female Employees: 1082 (estimated)

硫化锑安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H332-H411

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
R36/37/38;R20/21/22

[ 安全声明 (欧洲) ]:
S36/37/39-S26

[ 危险品运输编码 ]:
UN 1549 6.1/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
CC9450000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2830902000

硫化锑制备

【方法一】
制备方法有三种：天然太后加工法、锑白转化法和直接化合法。
天然矿加工法。天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。
锑白转化法。反应方程式：
Sb2O3+4Na2S+Ca(OH)2+3H2O→Sb2S3+8NaOH+CaS
操作方法：将Sb2O3 1.80kg、Ca(OH)2 0.6kg、H2O 6kg混合后，在80℃加热1h。将2.41kg 60%Na2S溶解在3L水中配成Na2S溶液，在搅拌下，于80℃下，在30min内将此Na2S溶液加入上述混合物中，再维持搅拌30min。然后用30%的HCl在3h内酸化至pH为0.4。升温至95℃，再搅拌3h，降温、过滤、洗涤、干燥，制得Sb2S3颜料。
直接化合法。反应方程式：
3S+2Sb→Sb2S3
操作方法：将金属锑高温熔化后，向其中通入硫蒸气，直接化合生成三硫化二锑。硫的用量为化学计量的103%～115%，搅拌反应0.3～1h，反应温度维持在650～850℃。

硫化锑海关

[ 海关编码 ]: 2830902000

硫化锑文献

Nanoscale ferroelectric and piezoelectric properties of Sb2S3 nanowire arrays.

Nano Lett. 12(2) , 868-72, (2012)

We report the first observation of piezoelectricity and ferroelectricity in individual Sb(2)S(3) nanowires embedded in anodic alumina templates. Switching spectroscopy-piezoresponse force microscopy (...

Improving bone marrow scintigraphy. A clinical and experimental study.

Acta Radiol. Suppl. 385 , 1-24, (1993)

Today bone marrow scintigraphy is performed by imaging either the reticuloendothelial system by means of colloids or the hematopoietic marrow with granulocytes. When visualizing the marrow with radiol...

Antimony trioxide and antimony trisulfide.

IARC Monogr. Eval. Carcinog. Risks Hum. 47 , 291-305, (1989)

更多文献

硫化锑