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吡菌磷

吡菌磷用途

Pyrazophos is an organic compound used as a fungicide and an insecticide.

吡菌磷名称

[ CAS 号 ]:
13457-18-6

[ 中文名 ]:
吡菌磷

[ 英文名 ]:
Afugan

[中文别名 ]:

定菌磷

[英文别名 ]:

PYRAZOPHOS
EINECS 236-656-1
Curamil
MFCD00055494
Afugan

吡菌磷物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 熔点 ]:
51℃

[ 分子式 ]:
C₁₄H₂₀N₃O₅PS

[ 分子量 ]:
373.365

[ 精确质量 ]:
373.086121

[ PSA ]:
126.08000

[ LogP ]:
3.01

[ 折射率 ]:
1.596

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

吡菌磷MSDS

详细MSDS(安全技术说明书)

吡菌磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TF2035000

CHEMICAL NAME :: Phosphorothioic acid, O,O-diethyl ester, O-ester with (6-ethoxycarbonyl-5-methyl) pyrazolo(1,5-a)pyrimidin-2-ol

CAS REGISTRY NUMBER :: 13457-18-6

LAST UPDATED :: 199612

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C14-H20-N3-O5-P-S

MOLECULAR WEIGHT :: 373.40

WISWESSER LINE NOTATION :: T56 ANN FNJ COPS&O2&O2 G1 HVO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 218 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KHZDAN Khigiena i Zdraveopazvane. Hygiene and Sanitation. (Hemus, Blvd. Russki 6, Sofia, Bulgaria) V.9- 1966- Volume(issue)/page/year: 23,538,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,734,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 435 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1266,1989

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 118 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,734,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 184 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1266,1989 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 53,99,1974

吡菌磷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H332-H410

[ 警示性声明 ]:
P273-P301 + P310-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
20/22-50/53

[ 安全声明 (欧洲) ]:
36/37-46-60-61

[ 危险品运输编码 ]:
UN 2783

[ RTECS号 ]:
TF2035000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

吡菌磷制备

2-羰基甲基-2-乙氧基丙烯酸乙酯与3-氨基吡唑酮-5反应制得O-6-乙氧羰基-5-甲基-2-羟基吡唑基［1.5a］并嘧啶。然后在缚酸剂碳酸钠存在下，于50℃与犗，O-二乙基硫代磷酰氯反应，合成吡菌磷。3-氨基吡啶酮-5的制备可由下式表示：

吡菌磷文献

[Biochemical changes in the myocardium in experimental chronic pirazofos poisoning].

Probl. Khig. 10 , 52-8, (1985)

The authors investigate the 12 month effect of the organophosphorus pesticide "Pyrazophos", in the myocardium status of albino male rats treated per os by 1/20, 1/100, and 1/200 LD50 of the preparatio...

Removal of pyrazophos from treated fabric using household laundering.

Bull. Environ. Contam. Toxicol. 42(5) , 687-90, (1989)

Pesticide residues in artichokes: effect of different head shape.

J. Environ. Sci. Health B 31(6) , 1189-99, (1996)

Residues of three pesticides (dimethoate, parathion, and pyrazophos) in two artichoke cultivars, Masedu and Spinoso sardo, were investigated. The amount of pesticides in artichokes was greatly affecte...

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吡菌磷