<生产厂家价格>

高氯酸镍(II)六水合物

高氯酸镍(II)六水合物名称

[ CAS 号 ]:
13520-61-1

[ 中文名 ]:
高氯酸镍六水合物

[ 英文名 ]:
nickel(ii) perchlorate hexahydrate

[中文别名 ]:

[英文别名 ]:

EINECS 237-124-1
MFCD00149804
Nickel(II) perchlorate hexahydrate

高氯酸镍(II)六水合物物理化学性质

[ 熔点 ]:
140 °C(lit.)

[ 分子式 ]:
Cl₂H₁₂NiO₁₄

[ 分子量 ]:
365.68600

[ 精确质量 ]:
363.89600

[ PSA ]:
203.92000

[ LogP ]:
0.04280

[ 折射率 ]:
1.55

[ 储存条件 ]:
室温，密封，干燥

[ 水溶解性 ]:
不同温度(℃)时每100毫升水中的溶解克数: 105g/0℃;107g/10℃;110g/20℃;113g/30℃;117g/40℃

高氯酸镍(II)六水合物MSDS

详细MSDS(安全技术说明书)

高氯酸镍(II)六水合物毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SC9550000

CHEMICAL NAME :: Perchloric acid, nickel(2+) salt, hexahydrate

CAS REGISTRY NUMBER :: 13520-61-1

LAST UPDATED :: 199712

DATA ITEMS CITED :: 30

MOLECULAR FORMULA :: Cl2-O8.Ni.6H2-O

MOLECULAR WEIGHT :: 365.73

WISWESSER LINE NOTATION :: NI G-O4*2 &QH 6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 14,512,1966 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

高氯酸镍(II)六水合物安全信息

[ 符号 ]:

GHS05, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H317-H334-H341-H350i-H360D-H372-H410

[ 警示性声明 ]:
P201-P261-P280-P284-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P2 (EN 143) respirator cartridges;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
O: Oxidizing agent;T: Toxic;

[ 风险声明 (欧洲) ]:
R49

[ 安全声明 (欧洲) ]:
S53-S16-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 1481 5.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
SC9550000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

高氯酸镍(II)六水合物制备

把稍过量的NiO与58％的高氯酸溶液混合。过滤后蒸发滤液到开始结晶。将溶液冷却至20℃，析出六水高氯酸镍。

高氯酸镍(II)六水合物文献

Synthesis and Characterization of a Series of Edge-Sharing Octahedral-Tetrahedral-Octahedral Linear Trinuclear Complexes [M(3)(L1O)(4)](2+), Where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+) and L1OH Is the Heteroscorpionate Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane.

Inorg. Chem. 37 , 2263, (1998)

The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O...

Nickel (II)-2, 2'-dipyridylamine system. I. Synthesis and stereochemistry of the complexes. Hurley TJ and Robinson MA.

Inorg. Chem. 7(1) , 33-38, (1968)

A new method for enol lactone synthesis by a Michael addition/cyclization sequence. Itoh K and Kanemasa S.

Tetrahedron Lett. 44(9) , 1799-1802, (2003)

更多文献