醋酸铜
醋酸铜用途
用作色层分析试剂
【用途二】
分析试剂，有机合成催化剂，杀虫剂、杀菌剂、印染固色剂，制备巴黎绿的中间体。
醋酸铜名称
[ CAS 号 ]:
142-71-2
[ 中文名 ]:
乙酸铜
[ 英文名 ]:
Copper(II) acetate
[中文别名 ]:
[英文别名 ]:
- acetic acid copper(2+) salt (2:1)
- copper,diacetate
- MFCD00008690
- copper(2+) acetate
- EINECS 205-553-3
- copper(II) acetate
- cupric acetate
- Copper(II)acetate
醋酸铜物理化学性质
[ 密度 ]:
1.068g/cm3
[ 沸点 ]:
117.1ºC at 760 mmHg
[ 熔点 ]:
115ºC
[ 分子式 ]:
C2H4CuO2++
[ 分子量 ]:
123.59800
[ 闪点 ]:
40ºC
[ 精确质量 ]:
122.95100
[ PSA ]:
37.30000
[ LogP ]:
0.08840
[ 外观性状 ]:
绿色结晶粉末
[ 蒸汽密度 ]:
6.9 (vs air)
[ 储存条件 ]:
库房通风低温干燥,与酸类分开存放
醋酸铜MSDS
醋酸铜毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AG3480000
- CHEMICAL NAME :
- Acetic acid, copper(2+) salt
- CAS REGISTRY NUMBER :
- 142-71-2
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 41
- MOLECULAR FORMULA :
- C4-H6-O4.Cu
- MOLECULAR WEIGHT :
- 181.64
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 501 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 14700 ug/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Musculoskeletal - joints Tumorigenic - active as anti-cancer agent Biochemical - Metabolism (Intermediary) - effect on inflammation or mediation of inflammation
- REFERENCE :
- PMDCAY Progress in Medical Chemistry. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1961- Volume(issue)/page/year: 15,211,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 17100 ug/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 196 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2500 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 30,771,1981
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 20 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 56 mg/kg/7D-I
- TOXIC EFFECTS :
- Blood - other changes Nutritional and Gross Metabolic - changes in metals, not otherwise specified Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes
- REFERENCE :
- BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 33,92,1984 ** REPRODUCTIVE DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- DOSE :
- 40 mg/kg
- SEX/DURATION :
- female 7-10 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Fertility - other measures of fertility
- REFERENCE :
- CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1849- Volume(issue)/page/year: 166,1237,1972 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FRANCE:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4 mg(Cu)/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Cu)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84332 No. of Facilities: 139 (estimated) No. of Industries: 4 No. of Occupations: 5 No. of Employees: 565 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84332 No. of Facilities: 550 (estimated) No. of Industries: 10 No. of Occupations: 13 No. of Employees: 15459 (estimated) No. of Female Employees: 10534 (estimated)
醋酸铜安全信息
[ 符号 ]:
GHS05, GHS07, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302-H314-H410
[ 警示性声明 ]:
P260-P280-P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful;N:Dangerousfortheenvironment;
[ 风险声明 (欧洲) ]:
R22;R36/37/38;R50/53
[ 安全声明 (欧洲) ]:
S26-S60-S61
[ 危险品运输编码 ]:
UN 3077
[ WGK德国 ]:
3
[ RTECS号 ]:
AG3480000
[ 危险类别 ]:
9.0
醋酸铜合成路线
醋酸铜上下游产品
醋酸铜上游产品
醋酸铜下游产品
醋酸铜制备
1.将50g五水合硫酸铜溶于500ml水中，过滤，另取57g十水合碳酸钠溶于240ml水，加热至60℃，慢慢加入硫酸铜溶液，并不断搅拌。静置，滤出沉淀，用热水洗涤至无硫酸为止，将沉淀放在300ml水中，加入2ml氨水搅拌，静置，倾出上层溶液，如此洗涤、沉淀数次。在烧杯中加入180ml水，热至60℃，加入22g冰醋酸，然后加入上述洗好的碱式碳酸铜，直至容器底部略有剩余。过滤，滤液蒸发浓缩至原体积的1/3时，冷却，过滤，用2ml水洗涤，于室温干燥，得成品。母液继续蒸发，并在快出结晶时加入5ml25%乙酸，又可获得部分成品。其得32-35g。
2.将一水醋酸铜（Ⅱ）加热至105℃，或用一水醋酸铜与醋酸酐加热回流，冷却后过滤，将所得晶体放在置有固体氢氧化钾或浓硫酸的真空保干器中干燥。
3.无水醋酸铜可通过在90 oC加热或在醋酸酐溶液中回流然后乙醚洗涤制备而来。
醋酸铜文献
Nanoscale 6(15) , 8720-5, (2014)
Continuous synthesis of Pd@Pt and Cu@Ag core-shell nanoparticles was performed using flow processes including microwave-assisted Pd (or Cu) core-nanoparticle formation followed by galvanic displacemen...
Hybrid nanostructured C-dot decorated Fe3O4 electrode materials for superior electrochemical energy storage performance.Dalton Trans. 44 , 9221-9, (2015)
Research on energy storage devices has created a niche owing to the ever increasing demand for alternative energy production and its efficient utilisation. Here, a novel composite of Fe3O4 nanospheres...
Spherulitic copper-copper oxide nanostructure-based highly sensitive nonenzymatic glucose sensor.Int. J. Nanomedicine 10 Spec Iss , 165-78, (2015)
In this work, three different spherulitic nanostructures Cu-CuOA, Cu-CuOB, and Cu-CuOC were synthesized in water-in-oil microemulsions by varying the surfactant concentration (30 mM, 40 mM, and 50 mM,...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：无水醋酸铜
公司名：南通润丰石油化工有限公司
区域：南通市崇川区
价格：
￥需询单/1kg
￥需询单/1ton
联系人：曹经理
产品详情：醋酸铜
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥168.0/100g
￥568.0/500g
联系人：刘佳
产品详情：无水醋酸铜
公司名：上海创赛科技有限公司
区域：上海市嘉定区
价格：
￥75.0/25g
￥136.0/100g
￥490.0/500g
￥1693.0/2500g
联系人：夏言
产品详情：[Perfemiker]无水醋酸铜,AR.98.0%
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥1675.9/3kg
￥368.9/100g
￥204.9/25g
￥1626.9/25g
联系人：阿拉丁
产品详情：无水醋酸铜
查看所有供应商请点击：
相关化合物
【醋酸铜】化源网提供醋酸铜CAS号142-71-2，醋酸铜MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询醋酸铜上化源网，专业又轻松。>>电脑版：醋酸铜
标题：醋酸铜_MSDS_用途_密度_醋酸铜CAS号【142-71-2】_化源网 地址：https://www.chemsrc.com/amp/cas/142-71-2_675369.html