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S-2,2'-二苯基-3,3'-(4-联菲酚)

S-2,2'-二苯基-3,3'-(4-联菲酚)名称

[ CAS 号 ]:
147702-15-6

[ 中文名 ]:
(S)-2,2'-二苯基-(4-联菲酚)

[ 英文名 ]:
(S)-VAPOL

[中文别名 ]:

S-2,2'-二苯基-3,3'-(4-联菲酚)

[英文别名 ]:

S-2,2'-二苯基-3,3'-(4-联菲酚)物理化学性质

[ 密度 ]:
1.287 g/cm3

[ 沸点 ]:
712.173ºC at 760 mmHg

[ 熔点 ]:
185-191ºC

[ 分子式 ]:
C₄₁H₂₈Cl₂O₂

[ 分子量 ]:
623.566

[ 闪点 ]:
298.408ºC

[ 精确质量 ]:
622.146606

[ PSA ]:
40.46000

[ LogP ]:
12.13310

[ 外观性状 ]:
白色至淡黄色粉末

[ 储存条件 ]:
室温

S-2,2'-二苯基-3,3'-(4-联菲酚)MSDS

S-2,2'-二苯基-3,3'-(4-联菲酚)安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351

[ 警示性声明 ]:
P281

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
37/38-40-41

[ 安全声明 (欧洲) ]:
26-36/37/39-36/37-24/25-23

[ 危险品运输编码 ]:
NONH for all modes of transport

S-2,2'-二苯基-3,3'-(4-联菲酚)合成路线

S-2,2'-二苯基-3,3'-(4-联菲酚)上下游产品

S-2,2'-二苯基-3,3'-(4-联菲酚)上游产品

S-2,2'-二苯基-3,3'-(4-联菲酚)下游产品

S-2,2'-二苯基-3,3'-(4-联菲酚)文献

New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.

Org. Lett. 7 , 367, (2005)

[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo...

Highly enantioselective deracemization of linear and vaulted biaryl ligands.

Org. Lett. 5 , 1813, (2003)

[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ...

Bao. J. et al.

J. Am. Chem. Soc. 118 , 3392, (1996)

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