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二羰基乙酰丙酮铑(I)

二羰基乙酰丙酮铑(I)名称

[ CAS 号 ]:
14874-82-9

[ 中文名 ]:
二羰基乙酰丙酮铑(I)

[ 英文名 ]:
Dicarbonylacetylacetonato rhodium(I)

[中文别名 ]:

[英文别名 ]:

Acetylacetonatorhodium(I) dicarbonyl
Dicarbonylacetylacetonato rhodium(I)
Dicarbonyl(2,4-pentanedionato)rhodium(I)
EINECS 238-947-9
MFCD00009884

二羰基乙酰丙酮铑(I)物理化学性质

[ 熔点 ]:
154-156ºC

[ 分子式 ]:
C₇H₇O₄Rh

[ 分子量 ]:
258.034

[ 精确质量 ]:
257.939941

[ PSA ]:
26.30000

[ LogP ]:
0.54410

[ 外观性状 ]:
红色/绿色结晶粉末

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

二羰基乙酰丙酮铑(I)MSDS

详细MSDS(安全技术说明书)

二羰基乙酰丙酮铑(I)安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H317-H319-H335

[ 补充危害声明 ]:
Risk of explosion if heated under confinement.

[ 警示性声明 ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
UN 3282

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

二羰基乙酰丙酮铑(I)文献

Frequency-domain time-resolved four wave mixing spectroscopy of vibrational coherence transfer with single-color excitation.

J. Phys. Chem. A 112(28) , 6320-9, (2008)

Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acet...

Two-dimensional time-frequency ultrafast infrared vibrational echo spectroscopy.

Phys. Rev. Lett. 86(17) , 3899-902, (2001)

2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-...

Horvath, I.T. et al.

J. Am. Chem. Soc. 120 , 3133, (1998)

更多文献