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六氟磷酸四乙氰铜四氟硼酸盐

六氟磷酸四乙氰铜四氟硼酸盐名称

[ CAS 号 ]:
15418-29-8

[ 中文名 ]:
四氟硼酸四(乙腈)铜(I)

[ 英文名 ]:
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)

[中文别名 ]:

[英文别名 ]:

Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)
acetonitrile,copper(1+),tetrafluoroborate

六氟磷酸四乙氰铜四氟硼酸盐物理化学性质

[ 熔点 ]:
164 °C(dec.)

[ 分子式 ]:
C₈H₁₂BCuF₄N₄

[ 分子量 ]:
314.558

[ 精确质量 ]:
314.038727

[ PSA ]:
95.16000

[ LogP ]:
3.41702

[ 外观性状 ]:
固体;White to Almost white powder to crystal

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

六氟磷酸四乙氰铜四氟硼酸盐MSDS

详细MSDS(安全技术说明书)

六氟磷酸四乙氰铜四氟硼酸盐安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 1759 8/PG 2

[ 包装等级 ]:
III

六氟磷酸四乙氰铜四氟硼酸盐文献

Enantioselective aziridination using copper complexes of biaryl Schiff bases.

J. Org. Chem. 67 , 3450, (2002)

Racemic 2,2'-diamino-6,6'-dimethylbiphenyl is resolved using simulated moving bed chromatography, and the absolute configuration of the enantiomers is confirmed via the X-ray crystal structure of a de...

Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers. Preparation of alpha,alpha'-disubstituted beta,gamma-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations.

Org. Lett. 7 , 1255, (2005)

[reaction: see text] Peptide-based chiral ligands, readily prepared from commercially available materials, are used to promote Cu-catalyzed asymmetric allylic alkylations of alpha,beta-unsaturated est...

Stoichiometry and cluster specificity of copper binding to metallothionein: homogeneous metal clusters.

Biochem. J. 317 ( Pt 2) , 395-402, (1996)

Experiments were done to define the stoichiometry of binding of Cu(I) to metallothionein (MT) and to determine its sites of binding in mixed-metal species. Spectrophotometric titrations of rabbit live...

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