乙烯基膦酸

乙烯基膦酸用途

用作喷墨用油墨的添加剂，因本品可以降低表面张力，而起到分散剂的作用，在油墨中加入本品聚合物，可以降低油墨粘度，同时使颜料不致沉淀；用作拔染染料助剂；本品与丙烯酰胺的聚合物，可用作含水量大、膨润性高的高粘度触变型胶囊，此种胶囊可用作高吸水性卫生材料；此种聚合物还可用作酸溶性涂料及石油井防渗水剂；本品的共聚物还可用作电泳涂料；本品一个重要的用途是用作口腔医护品，防止牙垢的生成，防治牙龈炎。

乙烯基膦酸名称

[ CAS 号 ]:
1746-03-8

[ 中文名 ]:
乙烯基膦酸

[ 英文名 ]:
Vinylphosphonic acid

[中文别名 ]:

[英文别名 ]:

Vinylphosphonsure
ethylenephosphonicacid
Vinylphosphonic Acid
ethenephosphonicacid
VINYLPHOSPHONIC ACID,PURE
vinyl-phosphonicaci
vinylphosphonate
EINECS 217-123-2
vynilphosphonic acid
vinyl phosphonic acid

乙烯基膦酸物理化学性质

[ 密度 ]:
1.389 g/mL at 25 °C(lit.)

[ 沸点 ]:
266.2ºC at 760mmHg

[ 熔点 ]:
41-45 °C(lit.)

[ 分子式 ]:
C₂H₅O₃P

[ 分子量 ]:
108.03300

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
107.99800

[ PSA ]:
67.34000

[ LogP ]:
0.30760

[ 外观性状 ]:
液体;Colorless to Light yellow clear liquid

[ 蒸汽压 ]:
0.00253mmHg at 25°C

[ 折射率 ]:
n20/D 1.473

[ 储存条件 ]:
室温

[ 水溶解性 ]:
水溶性：可溶

乙烯基膦酸MSDS

详细MSDS(安全技术说明书)

乙烯基膦酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SZ7903500

CHEMICAL NAME :: Phosphonic acid, ethenyl-

CAS REGISTRY NUMBER :: 1746-03-8

BEILSTEIN REFERENCE NO. :: 1741622

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C2-H5-O3-P

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 39,380,1991

乙烯基膦酸安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
SZ7903500

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2931900090

乙烯基膦酸制备

(1)以乙烯及三氯化磷为原料，氧化，生成1- 二氯磷酰基 2- 氯乙烷，水解，可制得。（ 2 ）以环氧乙烷和三氯化磷为原料，也可经 1- 二氯磷酰基 -2- 氯乙烷制得。

乙烯基膦酸海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

乙烯基膦酸文献

Improving some selected properties of dental polyacid-modified composite resins.

Dent. Mater. 27(10) , 997-1002, (2011)

Polyacid-modified composite resins (compomers) are restorative dental materials that exhibit certain features of traditional dental composites and glass-ionomer cements. The aim of this paper was to d...

Commercially available 5'-DMT phosphoramidites as reagents for the synthesis of vinylphosphonate-linked oligonucleic acids.

Org. Lett. 3(21) , 3365-7, (2001)

[reaction: see text]. Commercially available cyanoethyl phosphoramidites derived from T, d(C), d(A), and d(G) were hydrolyzed (1H-tetrazole, MeCN/H2O) to give the corresponding H-phosphonates in excel...

An all-in-one adhesive does not etch beyond hybrid layers.

J. Dent. Res. 89(5) , 482-7, (2010)

Continuous etching of aggressive all-in-one adhesives occurs in wet dentin tubules after polymerization of the adhesives. This study challenged the hypothesis that unpolymerized acidic monomers from a...

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