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(S)-4,12-双(二苯基膦)[2.2]对环芳烷

(S)-4,12-双(二苯基膦)[2.2]对环芳烷名称

[ CAS 号 ]:
192463-40-4

[ 中文名 ]:
(S)-4,12-二(二苯基膦)溴[2.2]对环芳

[ 英文名 ]:
Bisdiphenylphosphinoparacyclophane

[中文别名 ]:

[英文别名 ]:

(S)-Phanephos
<2.2>PHANEPHOS
(S)-Phanephos,ee
4-FLUOROBENZOYLACETONITRILE N-BOC-4-OXO-L-PROLINE
(S)-(+)-4,12-Bis(D
Bisdiphenylphosphinoparacyclophane
4,12-bis(diphenylphosphino)[2.2]paracyclophane
(R)-PHANEPHOS

(S)-4,12-双(二苯基膦)[2.2]对环芳烷物理化学性质

[ 熔点 ]:
222-225ºC

[ 分子式 ]:
C₄₀H₃₄P₂

[ 分子量 ]:
576.64500

[ 精确质量 ]:
576.21400

[ PSA ]:
27.18000

[ LogP ]:
7.08680

[ 外观性状 ]:
白色至灰白色固体

[ 储存条件 ]:
2-8°C

(S)-4,12-双(二苯基膦)[2.2]对环芳烷MSDS

详细MSDS(安全技术说明书)

(S)-4,12-双(二苯基膦)[2.2]对环芳烷安全信息

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

(S)-4,12-双(二苯基膦)[2.2]对环芳烷文献

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Org. Lett. 2 , 4173, (2000)

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantiosel...

J. Am. Chem. Soc. 119 , 6207, (1997)

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