磷化铝
磷化铝用途
杀虫剂,主要用于粮仓熏蒸
【用途二】
为熏蒸杀虫剂,既能熏蒸原粮、成品粮,又能熏蒸种子粮和各种仓储器材。也用于其他密闭场所杀虫、鼠洞灭鼠和树干灭天牛等。粮食熏蒸时用量为10~30 g/t粮;仓库熏蒸时一般用量为1~4片/m3。
磷化铝名称
[ CAS 号 ]:
20859-73-8
[ 中文名 ]:
磷化铝
[ 英文名 ]:
Aluminum phosphide
[中文别名 ]:
[英文别名 ]:
- EINECS 244-088-0
- Detia
- Celphos
- al-phos
- MFCD00046171
- celphine
- fumitoxin
- Talunex
- delicia
- aluminum phosphide
磷化铝物理化学性质
[ 密度 ]:
2.42
[ 熔点 ]:
2000℃
[ 分子式 ]:
AlP
[ 分子量 ]:
57.95
[ LogP ]:
0.55080
[ 外观性状 ]:
黄色或灰色晶体
[ 储存条件 ]:
库房通风低温干燥,与酸分开存放
[ 稳定性 ]:
Flammable solid. Contact with acids liberates highly toxic gas (phosphine). Incompatible with acids, moisture, oxidizing agents.
磷化铝MSDS
磷化铝毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BD1400000
- CHEMICAL NAME :
- Aluminum phosphide
- CAS REGISTRY NUMBER :
- 20859-73-8
- LAST UPDATED :
- 199803
- DATA ITEMS CITED :
- 22
- MOLECULAR FORMULA :
- Al-P
- MOLECULAR WEIGHT :
- 57.95
- WISWESSER LINE NOTATION :
- AL P
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - woman
- DOSE/DURATION :
- 60 mg/kg
- TOXIC EFFECTS :
- Vascular - other changes Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - gastritis
- REFERENCE :
- HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 21 mg/kg
- TOXIC EFFECTS :
- Vascular - other changes Gastrointestinal - gastritis
- REFERENCE :
- HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - woman
- DOSE/DURATION :
- 180 mg/kg
- TOXIC EFFECTS :
- Cardiac - pulse rate increase, without fall in BP Liver - jaundice, other or unclassified Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
- REFERENCE :
- HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 86 mg/kg
- TOXIC EFFECTS :
- Behavioral - coma Vascular - other changes Gastrointestinal - nausea or vomiting
- REFERENCE :
- HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 2800 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,38,1976/1977 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84460 No. of Facilities: 280 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 12600 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84460 No. of Facilities: 190 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 623 (estimated)
磷化铝安全信息
[ 危害码 (欧洲) ]:
T+,F,N
[ 风险声明 (欧洲) ]:
R15/29
[ 安全声明 (欧洲) ]:
S3/9/14-S30-S36/37-S45-S61
[ 危险品运输编码 ]:
1397
[ 包装等级 ]:
I
[ 危险类别 ]:
4.3
[ 海关编码 ]:
2848000010
磷化铝制备
1.赤磷和铝粉混合后,经高温煅烧,即得磷化铝。
2.本品可由赤磷和铝粉按比例混料,均匀混合后点火燃烧反应生成。反应物经粉碎、加入缓释剂氨基甲酸铵和黏结剂混合后压片成品。
磷化铝海关
[ 海关编码 ]: 2848000010
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相关化合物
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