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庚烯磷

庚烯磷用途

庚烯磷是70年代开发的新型有机磷杀虫剂，具有消毒、触杀和很强的内吸活性，用于防治杀灭豆蚜，还用于果树蔬菜蚜虫的防治。其最突出的特点是高效、持效短、残留量低，所以最适用于临近收获期防治害虫。此外，它也是猪、狗、牛、羊、兔等体外寄生虫的有效防治剂。

庚烯磷名称

[ CAS 号 ]:
23560-59-0

[ 中文名 ]:
庚烯磷

[ 英文名 ]:
heptenophos

[中文别名 ]:

[英文别名 ]:

庚烯磷物理化学性质

[ 密度 ]:
1.36g/cm3

[ 沸点 ]:
289.3ºC at 760mmHg

[ 熔点 ]:
25°C

[ 分子式 ]:
C9H12ClO4P

[ 分子量 ]:
250.61600

[ 闪点 ]:
160.2ºC

[ 精确质量 ]:
250.01600

[ PSA ]:
54.57000

[ LogP ]:
3.06020

[ 外观性状 ]:
liquid

[ 蒸汽压 ]:
0.004mmHg at 25°C

[ 折射率 ]:
1.518

[ 储存条件 ]:
APPROX 4°C

庚烯磷MSDS

详细MSDS(安全技术说明书)

庚烯磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TB8545000
CHEMICAL NAME :
Phosphoric acid, (7-chloro-bicyclo(3.2.0)hepta-2,6-dien-6-yl) dimethyl ester
CAS REGISTRY NUMBER :
23560-59-0
LAST UPDATED :
199612
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C9-H12-Cl-O4-P
MOLECULAR WEIGHT :
250.63
WISWESSER LINE NOTATION :
L45 BU EUTJ BOPO&O1&O1 CG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
96 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,11,1977
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A226,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - muscle contraction or spasticity Gastrointestinal - hypermotility, diarrhea
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - muscle contraction or spasticity Gastrointestinal - hypermotility, diarrhea
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TGANAK Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1967- Volume(issue)/page/year: 16(1),45,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,39,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
17 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,467,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
379 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(5),72,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
117 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KSKZAN Khimiya v Sel'skom Khozyaistve. Chemistry in Agriculture. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1963- Volume(issue)/page/year: 16(2),59,1978 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
140 mg/kg/10D-I
TOXIC EFFECTS :
Biochemical - Neurotransmitters or modulators (putative) - catecholamine levels in CNS Biochemical - Neurotransmitters or modulators (putative) - dopamine at other sites
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(5),80,1984
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
378 mg/kg/12W-C
TOXIC EFFECTS :
Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984

庚烯磷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H312-H330-H410

[ 警示性声明 ]:
P260-P273-P284-P301 + P310 + P330-P304 + P340 + P310-P403 + P233

[ 危害码 (欧洲) ]:
T,N,Xn,F

[ 风险声明 (欧洲) ]:
25-50/53-52/53-36-20/21/22-11

[ 安全声明 (欧洲) ]:
S23;S26;S28;S37;S45;S60;S61;S36/S37

[ 危险品运输编码 ]:
UN 3018

[ RTECS号 ]:
TB8545000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2919900035

庚烯磷制备

1.二氯乙酰氯的制备 往反应瓶中加入二氯乙酸，在加热下滴加邻苯二甲酰氯，滴加毕，升温分馏，收集106-110℃馏分即得。2.7，7-二氯二环[3.2.0]庚-2-烯-6-酮的制备 在反应瓶中混合二氯乙酰氯、新鲜解聚得到的环戊二烯及戊烷组成的溶液。在氮气下搅拌加热回流并慢慢滴加三乙胺的戊烷溶液。加毕后回流几小时，得乳白色液。加入蒸馏水，以溶解三乙胺盐酸盐。分出水层，水层用戊烷抽提，合并有机层，经干燥、过滤，蒸去戊烷及多余的环戊二烯后，得粘稠的橙色液体，减压蒸馏，收集66-68℃（0.267kPa）的馏分即得。3.庚烯磷的制备 在反应瓶中加入7，7-二氯二环[3.2.0]庚-2-烯-6-酮及亚磷酸三甲酯，加热至适当温度后再保温反应几小时，然后减压蒸馏收集128-130℃（0.53kPa）馏分即得。配制成40%可湿性粉剂或25%、50%乳剂。 


庚烯磷海关

[ 海关编码 ]: 2919900090

[ 中文概述 ]:
HS:2919900090 其他磷酸酯及其盐（包括乳磷酸盐）（包括它们的卤化，磺化，硝化和亚硝化衍生物） 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

庚烯磷文献

[Distribution of chostaquick in the rat body after different ways of intake].

Gig. Sanit. (1) , 57-9, (1990)


更多文献

推荐生产厂家/供应商：

公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：庚烯磷

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥4739.0/500mg ￥需询单/1g ￥需询单/1g ￥需询单/1g

联系人：阿拉丁

产品详情：庚磷

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