三甲氧基硅烷
三甲氧基硅烷用途
是合成功能性有机硅化合物的重要中间体,用于粘合剂、涂料和有机硅改性高聚物,还可用作加氢还原试剂
三甲氧基硅烷名称
[ CAS 号 ]:
2487-90-3
[ 中文名 ]:
三甲氧基硅烷
[ 英文名 ]:
Trimethoxysilane
[中文别名 ]:
[英文别名 ]:
- Silane,trimethoxy
- trimethoxyorthosilane
- trimethoxy silane
- Trimethoxysilane
- trimethoxy-silan
- Trimethoxysilyl hydride
- EINECS 219-637-2
- MFCD00008340
- Silane, trimethoxy-
- trimethoxylsiloxane
三甲氧基硅烷物理化学性质
[ 密度 ]:
0.96 g/mL at 25 °C(lit.)
[ 沸点 ]:
81.0±0.0 °C at 760 mmHg
[ 熔点 ]:
−115 °C(lit.)
[ 分子式 ]:
C3H10O3Si
[ 分子量 ]:
122.195
[ 闪点 ]:
-20.7±18.7 °C
[ 精确质量 ]:
122.039917
[ PSA ]:
27.69000
[ LogP ]:
3.11
[ 外观性状 ]:
无色透明液体
[ 蒸汽密度 ]:
>1 (vs air)
[ 蒸汽压 ]:
92.6±0.1 mmHg at 25°C
[ 折射率 ]:
n20/D 1.358(lit.)
[ 储存条件 ]:
Flammables area
[ 稳定性 ]:
May decompose upon exposure to air or water. Incompatible with strong oxidizing agents, strong bases, strong acids.
三甲氧基硅烷MSDS
三甲氧基硅烷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- VV6750000
- CHEMICAL NAME :
- Silane, trimethoxy-
- CAS REGISTRY NUMBER :
- 2487-90-3
- BEILSTEIN REFERENCE NO. :
- 1697990
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- C3-H10-O3-Si
- MOLECULAR WEIGHT :
- 122.22
- WISWESSER LINE NOTATION :
- 1O-SI-HO1&O1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1220,1986
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1220,1986 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 9330 uL/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 42 ppm/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 13,152,1993
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 6300 uL/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5 ppm/7H/4W-I
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - chronic pulmonary edema Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
- REFERENCE :
- EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0680-0347
三甲氧基硅烷安全信息
[ 符号 ]:
GHS02, GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H319-H330
[ 警示性声明 ]:
P210-P260-P284-P305 + P351 + P338-P310
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
F:Flammable;T+:Verytoxic;
[ 风险声明 (欧洲) ]:
R11;R26;R36
[ 安全声明 (欧洲) ]:
S16-S36/37/39-S45
[ 危险品运输编码 ]:
UN 3384 6.1/PG 1
[ WGK德国 ]:
3
[ RTECS号 ]:
VV6750000
[ 包装等级 ]:
I
[ 危险类别 ]:
6.1(a)
[ 海关编码 ]:
2931900090
三甲氧基硅烷上下游产品
三甲氧基硅烷上游产品
三甲氧基硅烷下游产品
三甲氧基硅烷制备
可由硅粉在铜催化剂存在下,与甲醇反应来制取。
三甲氧基硅烷海关
[ 海关编码 ]: 2931900090
[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
三甲氧基硅烷文献
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Abatement of aqueous anionic contaminants by thermo-responsive nanocomposites: (poly(N-isopropylacrylamide))-co-silylanized magnesium/aluminun layered double hydroxides.J. Colloid. Interface Sci. 448 , 65-72, (2015)
A series of novel thermo-responsive composite sorbents, were prepared by free-radical co-polymerization of N-isopropylacrylamide (NIPAm) and the silylanized Mg/Al layered double hydroxides (SiLDHs), n...
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