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异柳磷

异柳磷用途

Isofenphos is a pesticide residue found in plant based food that may have acute health risks for consumers.

异柳磷名称

[ CAS 号 ]:
25311-71-1

[ 中文名 ]:
异柳磷

[ 英文名 ]:
UNII:0514MAW53A

[中文别名 ]:

[英文别名 ]:

pyrfon
Amidocid
Amaze
ISOFENPHOS
EINECS 246-814-1
Pryfon
[14C]-Isofenphos
discus
AMAZE(R)
40sd

异柳磷物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
411.5±47.0 °C at 760 mmHg

[ 熔点 ]:
Less than -12ºC

[ 分子式 ]:
C₁₅H₂₄NO₄PS

[ 分子量 ]:
345.394

[ 闪点 ]:
202.7±29.3 °C

[ 精确质量 ]:
345.116364

[ PSA ]:
98.69000

[ LogP ]:
4.12

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.528

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

异柳磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VO4395500

CHEMICAL NAME :: Salicylic acid, isopropyl ester, O-ester with O-ethyl isopropylphosphoramidothioate

CAS REGISTRY NUMBER :: 25311-71-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C15-H24-N-O4-P-S

MOLECULAR WEIGHT :: 345.43

WISWESSER LINE NOTATION :: 1Y1&OVR DOPS&O2&MY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 28 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,118,1977

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 144 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A236,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 188 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,39,1978

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 91300 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 162 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C173,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 3 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - muscle weakness Gastrointestinal - changes in structure or function of salivary glands

REFERENCE :: BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 33,386,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 13 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 8,551,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2240 mg/kg/8W-I

TOXIC EFFECTS :: Liver - other changes Biochemical - Metabolism (Intermediary) - other proteins

REFERENCE :: IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 21,684,1983 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

异柳磷安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H312 + H332-H319-H412

[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
24/25-50/53

[ 安全声明 (欧洲) ]:
S36/37-S45-S60-S61

[ 危险品运输编码 ]:
3018

[ RTECS号 ]:
VO4395500

[ 包装等级 ]:
I

[ 危险类别 ]:
6.1(a)

[ 海关编码 ]:
2929909012

异柳磷制备

由乙基硫磷酰二氯、水杨酸异丙酯、异丙胺经下列反应而得。将水杨酸异丙酯、乙基硫代磷酰二氯和催化剂投入反应釜，搅拌冷却至 10 ℃ 左右。缓慢加入一部分氢氧化钠溶液，反应半小时后再将其余的氢氧化钠溶液和异丙胺同时缓慢均匀加入。加毕后再继续反应2h。然后加水和溶剂，搅拌后静置分出下层废水，上层粗油经减压蒸馏即得乙基异柳磷原油。将乙基硫代磷酰二氯用甲基硫代磷酰二氯代替，采用相似工艺可制得甲基异柳磷。原料消耗定额：水杨酸 350kg /t、异丙醇 580kg /t、硫酸 340kg /t、甲醇 720kg /t、异丙胺 130kg /t、三氯硫磷 380kg /t。

异柳磷海关

[ 海关编码 ]: 2929909012

[ 中文概述 ]:
2929909012 异柳磷、甲基异柳磷、丙胺氟磷等退税率:0.0% 监管条件:S(进出口农药登记证明)

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2929909012 isopropyl 2-((ethoxy(isopropylamino)phosphorothioyl)oxy)benzoate

异柳磷