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1,3-双(2,6-二异丙苯基)氯化咪唑鎓

1,3-双(2,6-二异丙苯基)氯化咪唑鎓名称

[ CAS 号 ]:
258278-25-0

[ 中文名 ]:
1,3-双(2,6-二异丙基苯基)咪唑氯盐

[ 英文名 ]:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

[中文别名 ]:

[英文别名 ]:

SIPr.HCl
MFCD07369796

1,3-双(2,6-二异丙苯基)氯化咪唑鎓物理化学性质

[ 熔点 ]:
289-293ºC(lit.)

[ 分子式 ]:
C₂₇H₃₉ClN₂

[ 分子量 ]:
427.065

[ 精确质量 ]:
426.280182

[ PSA ]:
6.25000

[ LogP ]:
7.39650

[ 外观性状 ]:
白色至黄色结晶粉末

[ 储存条件 ]:
室温

[ 水溶解性 ]:
可溶于：甲醇

1,3-双(2,6-二异丙苯基)氯化咪唑鎓MSDS

详细MSDS(安全技术说明书)

1,3-双(2,6-二异丙苯基)氯化咪唑鎓安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

1,3-双(2,6-二异丙苯基)氯化咪唑鎓文献

Palladium-(N-heterocyclic carbene) hydrogenation catalysts.

Angew. Chem. Int. Ed. Engl. 44 , 2026, (2005)

NHC-catalyzed ring expansion of oxacycloalkane-2-carboxaldehydes: a versatile synthesis of lactones.

Org. Lett. 11 , 891, (2009)

Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety of functionalized five-, six-, and seven-membered lactones can be formed efficie...

Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions.

J. Org. Chem. 4 , 2079, (2002)

[reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck couple...

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