1-溴环己烷羧酸甲酯

1-溴环己烷羧酸甲酯用途

Methyl 1-bromocyclohexanecarboxylate may be used in the improved method of preparation of methyl 3-oxo-1-cyclohexene-1-carboxylate.It may be used in the Reformatsky synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones.

1-溴环己烷羧酸甲酯名称

[ CAS 号 ]:
3196-23-4

[ 中文名 ]:
1-溴环己烷羧酸甲酯

[ 英文名 ]:
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE

[英文别名 ]:

methyl 1-bromocyclohexanecarboxylic acid
methyl 1-bromocyclohexylcarboxylate
MFCD00134214
methyl 1-bromo-cyclohexane-1-carboxylate
Methyl 1-bromocyclohexanecarboxylate
methyl 1-bromocyclohex-1-yl-1-carboxylate
1-Bromcyclohexancarbonsaeure-methylester

1-溴环己烷羧酸甲酯物理化学性质

[ 密度 ]:
1.39 g/mL at 25ºC(lit.)

[ 沸点 ]:
115-116ºC19 mm Hg(lit.)

[ 分子式 ]:
C₈H₁₃BrO₂

[ 分子量 ]:
221.09200

[ 闪点 ]:
222 °F

[ 精确质量 ]:
220.01000

[ PSA ]:
26.30000

[ LogP ]:
2.25720

[ 外观性状 ]:
无色液体

[ 折射率 ]:
n20/D 1.493(lit.)

[ 储存条件 ]:
室温

1-溴环己烷羧酸甲酯MSDS

详细MSDS(安全技术说明书)

1-溴环己烷羧酸甲酯安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
34-36/37

[ 安全声明 (欧洲) ]:
26-27-28-36/37/39-45

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ 包装等级 ]:
III

1-溴环己烷羧酸甲酯合成路线

详细合成路线

1-溴环己烷羧酸甲酯上下游产品

1-溴环己烷羧酸甲酯上游产品

1-溴环己烷羧酸甲酯下游产品

1-溴环己烷羧酸甲酯文献

Improved preparation of methyl 3-oxo-1-cyclohexene-1-carboxylate and its use in the synthesis of substituted 1, 5-cyclodecadienes. Lange GL and Otulakowski JA.

J. Org. Chem. 47(26) , 5093-96, (1982)

Reaction of Reformatsky reagent prepared from methyl 1-bromocyclohexanecarboxylate and zinc with substituted chalcones. Kirillov NF and Gavrilov AG.

Russ. J. Org. Chem. 44(7) , 963-4, (2008)

Reformatsky Synthesis of 16-Aryl-15-oxadispiro [5.1. 5.3] hexadecane-7, 14-diones. Kirillov NF and Shchepin VV.

Russ. J. Org. Chem. 37(9) , 1223-24, (2001)

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