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氯五氟苯

氯五氟苯用途

【用途一】
医药、农药、液晶材料中间体。

氯五氟苯名称

[ CAS 号 ]:
344-07-0

[ 中文名 ]:
氯五氟苯

[ 英文名 ]:
1-Chloro-2,3,4,5,6-pentafluorobenzene

[中文别名 ]:

[英文别名 ]:

EINECS 206-450-6
PENTAFLUOROCHLORO BENZENE
Chloropentafluorobenzene
chloropentafuorobenzene
MFCD00000534
Pentafluorophenyl chloride
Benzene, 1-chloro-2,3,4,5,6-pentafluoro-
Chloroperfluorobenzene
Benzene,chloropentafluoro
1-Chloro-2,3,4,5,6-pentafluorobenzene

氯五氟苯物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
123.8±35.0 °C at 760 mmHg

[ 熔点 ]:
18.1ºC

[ 分子式 ]:
C₆ClF₅

[ 分子量 ]:
202.509

[ 闪点 ]:
29.5±19.4 °C

[ 精确质量 ]:
201.960876

[ LogP ]:
2.28

[ 外观性状 ]:
固体。

[ 蒸汽压 ]:
15.8±0.2 mmHg at 25°C

[ 折射率 ]:
1.422

[ 储存条件 ]:
Refrigerator

氯五氟苯MSDS

氯五氟苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CZ1225500

CHEMICAL NAME :: Benzene, chloropentafluoro-

CAS REGISTRY NUMBER :: 344-07-0

LAST UPDATED :: 199701

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C6-Cl-F5

MOLECULAR WEIGHT :: 202.51

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >4840 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2500 mg/m3/6H/3W-I

TOXIC EFFECTS :: Liver - hepatitis (hepatocellular necrosis), diffuse Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2500 mg/m3/6H/3W-I

TOXIC EFFECTS :: Liver - other changes Liver - changes in liver weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 10500 mg/kg

SEX/DURATION :: female 6-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 62500 ug/L

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A187-233 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 2 mg/m3 JAN 1993

氯五氟苯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xn:Harmful;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R20

[ 安全声明 (欧洲) ]:
S23-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
CZ1225500

[ 海关编码 ]:
2903999090

氯五氟苯合成路线

氯五氟苯上下游产品

氯五氟苯上游产品

氯五氟苯下游产品

氯五氟苯海关

[ 海关编码 ]: 2903999090

[ 中文概述 ]:
2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

氯五氟苯文献

Gas chromatography with parallel hard and soft ionization mass spectrometry.

Rapid Commun. Mass Spectrom. 29(1) , 91-9, (2014)

Mass spectrometric identification of compounds in chromatography can be obtained from molecular masses from soft ionization mass spectrometry techniques such as field ionization (FI) and fragmentation...

Oxidative dehalogenation of perhalogenated benzenes by cytochrome P450 compound I.

Biochemistry 46(20) , 5924-40, (2007)

Resolution of the identity PBE (RI-PBE) and B3LYP density functional theory calculations are used to understand the cytochrome P450-catalyzed, Compound I-mediated oxidation of perchlorobenzenes, perfl...

Catalytic and Noncatalytic Ammonolysis of Chloropentafluorobenzene. Selivanova GA, et al.

Russ. J. Org. Chem. 37(3) , 404-9, (2001)

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