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2-氯-4H-1,3,2-苯并二氧磷-4-酮

2-氯-4H-1,3,2-苯并二氧磷-4-酮名称

[ CAS 号 ]:
5381-99-7

[ 中文名 ]:
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮

[ 英文名 ]:
2-chloro-4h-1,3,2-benzodioxaphosphorin-4-one

[中文别名 ]:

2-氯-4H-1,3,2-苯并二氧磷-4-酮

[英文别名 ]:

SalPCl Salicyl chlorophosphite
2-chloro-1,3,2-benzodioxaphosphinin-4-one
Salicylchlorophosphite
2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one
MFCD00013353

2-氯-4H-1,3,2-苯并二氧磷-4-酮物理化学性质

[ 沸点 ]:
127-128 °C11 mm Hg(lit.)

[ 熔点 ]:
36-40 °C(lit.)

[ 分子式 ]:
C₇H₄ClO₃P

[ 分子量 ]:
202.53200

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
201.95900

[ PSA ]:
49.12000

[ LogP ]:
2.70150

[ 外观性状 ]:
固体;White or Colorless to Orange to Green powder to lump to clear liquid

[ 储存条件 ]:
2-8°C

[ 稳定性 ]:
Water Sensitive

2-氯-4H-1,3,2-苯并二氧磷-4-酮MSDS

2-氯-4H-1,3,2-苯并二氧磷-4-酮安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R14;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S43-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 1

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2914700090

2-氯-4H-1,3,2-苯并二氧磷-4-酮合成路线

2-氯-4H-1,3,2-苯并二氧磷-4-酮上下游产品

2-氯-4H-1,3,2-苯并二氧磷-4-酮上游产品

2-氯-4H-1,3,2-苯并二氧磷-4-酮下游产品

2-氯-4H-1,3,2-苯并二氧磷-4-酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2-氯-4H-1,3,2-苯并二氧磷-4-酮文献

Enzymatic primer-extension with glycerol-nucleoside triphosphates on DNA templates.

PLoS ONE 4(3) , e4949, (2009)

Glycerol nucleic acid (GNA) has an acyclic phosphoglycerol backbone repeat-unit, but forms stable duplexes based on Watson-Crick base-pairing. Because of its structural simplicity, GNA is of particula...

How to get the most out of two phosphorus chemistries. Studies on H-phosphonates.

Acc. Chem. Res. 35 , 952, (2002)

The biological importance and practical significance of phosphate esters and their analogues have been the major driving forces for research in various areas of synthetic organic phosphorus chemistry....

Byun, H.-S.; Erukulla, R. K.; Bittman, R.

J. Org. Chem. 59 , 6495, (1994)

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