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2-苯基-1,3-二噻烷

2-苯基-1,3-二噻烷用途

聚合物/大分子半导体砌块

2-苯基-1,3-二噻烷名称

[ CAS 号 ]:
5425-44-5

[ 中文名 ]:
2-苯基-1,3-二噻烷

[ 英文名 ]:
1,3-Dithiane, 2-phenyl-

[英文别名 ]:

EINECS 226-568-1
2-phenyl-1,3-dithioane
2-Phenyl-m-dithiane
m-DITHIANE,2-PHENYL
1-phenyl-1,3-dithiane
MFCD00006656
1,3-Dithiane,2-phenyl

2-苯基-1,3-二噻烷物理化学性质

[ 密度 ]:
1.157g/cm3

[ 沸点 ]:
326.8ºC at 760mmHg

[ 熔点 ]:
72-74ºC(lit.)

[ 分子式 ]:
C₁₀H₁₂S₂

[ 分子量 ]:
196.33200

[ 闪点 ]:
158.3ºC

[ 精确质量 ]:
196.03800

[ PSA ]:
50.60000

[ LogP ]:
3.55530

[ 折射率 ]:
1.615

[ 储存条件 ]:
室温，干燥

2-苯基-1,3-二噻烷MSDS

2-苯基-1,3-二噻烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: JO5277000

CHEMICAL NAME :: m-Dithiane, 2-phenyl-

CAS REGISTRY NUMBER :: 5425-44-5

BEILSTEIN REFERENCE NO. :: 0130879

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C10-H12-S2

MOLECULAR WEIGHT :: 196.34

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 19,461,1984

2-苯基-1,3-二噻烷安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 安全声明 (欧洲) ]:
S22

[ 危险品运输编码 ]:
UN 3335

[ 海关编码 ]:
2934999090

2-苯基-1,3-二噻烷合成路线

2-苯基-1,3-二噻烷上下游产品

2-苯基-1,3-二噻烷上游产品

2-苯基-1,3-二噻烷下游产品

2-苯基-1,3-二噻烷海关

[ 海关编码 ]: 2934999090

[ 中文概述 ]:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-苯基-1,3-二噻烷文献

Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.

J. Am. Chem. Soc. 125 , 14435, (2003)

The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading...

Smith, A. B., III; Boldi, A. M.

J. Am. Chem. Soc. 119 , 6925, (1997)

Synthesis of 1-deuterioaldehydes. Benzaldehyde-1-D. Seebach D, et al.

J. Org. Chem. 31(12) , 4303-4, (1966)

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