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2-二环己基磷-2,4,6-三异丙基联苯

2-二环己基磷-2,4,6-三异丙基联苯用途

用作钯催化Suzuki偶联反应的配体，生成文朵灵的C-15类似物；用于钯催化2-卤代苯胺直接环化生成吲哚和色氨酸；区域规则性聚噻吩的合成。用于深入研究芳烃磺酸酯、芳基卤的钯催化胺化和酰胺化反应的配体。

2-二环己基磷-2,4,6-三异丙基联苯名称

[ CAS 号 ]:
564483-18-7

[ 中文名 ]:
2-二环己基磷-2,4,6-三异丙基联苯

[ 英文名 ]:
X-Phos

[中文别名 ]:

[英文别名 ]:

MFCD04117682
EINECS 270-588-3
XPhos
L6TJ APR BR BY1&1 DY1&1 FY1&1&&- AL6TJ
X-PHOS
5-BROMO-4-CHLORO-3-INDOLYL PHOSPHATE

2-二环己基磷-2,4,6-三异丙基联苯物理化学性质

[ 沸点 ]:
569.8±50.0 °C at 760 mmHg

[ 熔点 ]:
187-190 °C(lit.)

[ 分子式 ]:
C₃₃H₄₉P

[ 分子量 ]:
476.716

[ 闪点 ]:
317.7±36.4 °C

[ 精确质量 ]:
476.357178

[ PSA ]:
13.59000

[ LogP ]:
12.46

[ 外观性状 ]:
白色结晶粉末

[ 蒸汽压 ]:
0.0±1.5 mmHg at 25°C

[ 储存条件 ]:
室温，密封

[ 水溶解性 ]:
可溶于：氯仿

2-二环己基磷-2,4,6-三异丙基联苯MSDS

2-二环己基磷-2,4,6-三异丙基联苯安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H413

[ 警示性声明 ]:
P281

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26-S36/37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2902909090

2-二环己基磷-2,4,6-三异丙基联苯合成路线

2-二环己基磷-2,4,6-三异丙基联苯海关

[ 海关编码 ]: 2902909090

[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

2-二环己基磷-2,4,6-三异丙基联苯文献

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

更多文献

2-二环己基磷-2,4,6-三异丙基联苯

2-二环己基磷-2,4,6-三异丙基联苯用途

2-二环己基磷-2,4,6-三异丙基联苯名称

2-二环己基磷-2,4,6-三异丙基联苯物理化学性质

2-二环己基磷-2,4,6-三异丙基联苯MSDS

详细MSDS(安全技术说明书)

2-二环己基磷-2,4,6-三异丙基联苯安全信息

2-二环己基磷-2,4,6-三异丙基联苯合成路线

详细合成路线

2-二环己基磷-2,4,6-三异丙基联苯海关

2-二环己基磷-2,4,6-三异丙基联苯文献

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