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2-氮杂金刚烷-N-氧自由基

2-氮杂金刚烷-N-氧自由基用途

2-氮杂金刚烷-N-氧代 (AZADO) 可用于以下研究：用作木材纤维素氧化的催化剂。雅库酰胺 A（一种从海绵 Ceratopsion sp. 中提取的潜在细胞毒素）全合成的催化剂。作为 ( S )-缩水甘油氧化的氧化剂。

2-氮杂金刚烷-N-氧自由基名称

[ CAS 号 ]:
57625-08-8

[ 中文名 ]:
2-氮杂金刚烷-N-氧自由基

[ 英文名 ]:
AZADO

[英文别名 ]:

2-azaadamantan-N-oxyl
2-azaadamantane N-oxyl
2-azaadanantane N-oxyl

2-氮杂金刚烷-N-氧自由基物理化学性质

[ 熔点 ]:
182-189ºC (D)

[ 分子式 ]:
C₉H₁₄NO

[ 分子量 ]:
152.21400

[ 精确质量 ]:
152.10800

[ PSA ]:
3.24000

[ LogP ]:
1.53270

[ 外观性状 ]:
粉末

[ 储存条件 ]:
2-8°C

2-氮杂金刚烷-N-氧自由基MSDS

详细MSDS(安全技术说明书)

2-氮杂金刚烷-N-氧自由基安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
22

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
2933990090

2-氮杂金刚烷-N-氧自由基海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-氮杂金刚烷-N-氧自由基文献

TEMPO electromediated oxidation of some polysaccharides including regenerated cellulose fiber.

Biomacromolecules 11(6) , 1593-9, (2010)

Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of t...

A short scalable route to (-)-α-kainic acid using Pt-catalyzed direct allylic amination.

Chemistry 21(10) , 3937-41, (2015)

An increased supply of scarce or inaccessible natural products is essential for the development of more sophisticated pharmaceutical agents and biological tools, and thus the development of atom-econo...

Total synthesis and complete structural assignment of yaku'amide A.

J. Am. Chem. Soc. 135(14) , 5467-74, (2013)

Here we report the first total synthesis and the complete stereochemical assignment of yaku'amide A. Yaku'amide A (1) was isolated from a sponge Ceratopsion sp. as an extremely potent cytotoxin. Its s...

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