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一甲胺盐酸盐

一甲胺盐酸盐用途

【用途一】
用作分析试剂，也用于有机合成
【用途二】
分析试剂，有机合成。

一甲胺盐酸盐名称

[ CAS 号 ]:
593-51-1

[ 中文名 ]:
盐酸甲胺

[ 英文名 ]:
Methylamine hydrochloride

[中文别名 ]:

[英文别名 ]:

methanamine hydrochloride
Methyl-ammonium
metylamine hydrochloride
Methanamine, hydrochloride (1:1)
METHYLAMINE HCL
MONOMETHYLAMINE HCL
methylammonium chloride
Methanaminium chloride
Methylamine hydrochl
Methaniminium

一甲胺盐酸盐物理化学性质

[ 沸点 ]:
225-230 °C15 mm Hg(lit.)

[ 熔点 ]:
231-233 °C(lit.)

[ 分子式 ]:
CH₆ClN

[ 分子量 ]:
67.518

[ 闪点 ]:
225-230°C/15mm

[ 精确质量 ]:
67.018875

[ PSA ]:
26.02000

[ LogP ]:
1.07720

[ 外观性状 ]:
白色至淡黄褐色的固体

[ 储存条件 ]:
库房低温,通风,干燥,防火,与氧化剂,强酸分开存放

[ 稳定性 ]:
Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
soluble

一甲胺盐酸盐MSDS

一甲胺盐酸盐毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: PA0603000

CHEMICAL NAME :: Methanamine, hydrochloride

CAS REGISTRY NUMBER :: 593-51-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C-H5-N.Cl-H

MOLECULAR WEIGHT :: 67.53

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: INHTE5 Inhalation Toxicology. (Hemisphere Publishing Corp., c/o Taylor & Francis Inc., 1900 Frost Rd., Suite 101, Bristol, PA 19007) V.1- 1989- Volume(issue)/page/year: 2,29,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2160 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 97,1117,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 610 mg/kg/5D-I

TOXIC EFFECTS :: Blood - changes in leukocyte (WBC) count

REFERENCE :: JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 47,479,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4270 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

一甲胺盐酸盐安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
PA0603000

[ 海关编码 ]:
29211190

一甲胺盐酸盐合成路线

一甲胺盐酸盐上下游产品

一甲胺盐酸盐上游产品

一甲胺盐酸盐下游产品

一甲胺盐酸盐制备

1.甲胺溶液在冷却下加入化学纯盐酸，调至ph＝2～3，然后脱色过滤、减压浓缩后，再调ph＝2～3，冷却滤出结晶，即为成品。
反应式为：

一甲胺盐酸盐海关

[ 海关编码 ]: 2921110090

[ 中文概述 ]:
2921110090 甲胺，三甲胺及其盐。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: M.进口商品检验 N.出口商品检验

[ Summary ]:
HS: 2921110090. methylamine, di- or trimethylamine and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:ab(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. general tariff:30.0%

一甲胺盐酸盐文献

Characterization of stress-exposed granulocyte colony stimulating factor using ELISA and hydrogen/deuterium exchange mass spectrometry.

J. Am. Soc. Mass Spectrom. 25(10) , 1747-54, (2014)

Information on the higher-order structure is important in the development of biopharmaceutical drugs. Recently, hydrogen/deuterium exchange coupled with mass spectrometry (HDX-MS) has been widely used...

Methylamine utilization via the N-methylglutamate pathway in Methylobacterium extorquens PA1 involves a novel flow of carbon through C1 assimilation and dissimilation pathways.

J. Bacteriol. 196(23) , 4130-9, (2014)

Methylotrophs grow on reduced single-carbon compounds like methylamine as the sole source of carbon and energy. In Methylobacterium extorquens AM1, the best-studied aerobic methylotroph, a periplasmic...

Quantitative liquid chromatography-electrospray ionization-mass spectrometry analysis of amine-containing metabolites derivatized with cyanuric chloride and methylamine isotopologues.

J. Chromatogr. A. 1388 , 60-8, (2015)

Electrospray ionization (ESI) is the most useful interface for mass spectrometry associated with liquid chromatography (LC). However, analyses of polar metabolites become a challenge because the high ...

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