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仲丁基锂

仲丁基锂用途

【用途一】
有机催化反应。
【用途二】
有机催化反应

仲丁基锂名称

[ CAS 号 ]:
598-30-1

[ 中文名 ]:
仲丁基锂

[ 英文名 ]:
sec-Butyllithium solution

[中文别名 ]:

[英文别名 ]:

lithium,butane
EINECS 209-927-7
MFCD00009323

仲丁基锂物理化学性质

[ 密度 ]:
0.769 g/mL at 25 °C

[ 分子式 ]:
C₄H₉Li

[ 分子量 ]:
64.05530

[ 闪点 ]:
1 °F

[ 精确质量 ]:
64.08640

[ LogP ]:
1.75410

[ 外观性状 ]:
透明淡黄色溶液

[ 储存条件 ]:
2-8°C

仲丁基锂MSDS

仲丁基锂安全信息

[ 符号 ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H250-H260-H304-H314-H336-H410

[ 警示性声明 ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R11;R15;R17;R34;R51/53;R65;R66;R67

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S43-S45-S60-S61-S62

[ 危险品运输编码 ]:
UN 3394 4.2/PG 1

[ WGK德国 ]:
2

[ 包装等级 ]:
I

[ 危险类别 ]:
4.3

仲丁基锂合成路线

仲丁基锂上下游产品

仲丁基锂上游产品

仲丁基锂下游产品

仲丁基锂制备

通过氯代异丁烷与金属锂在烃类溶剂中反应制备而来。

仲丁基锂文献

Thin films of homopolymers and cylinder-forming diblock copolymers under shear.

ACS Nano 8(8) , 8015-26, (2014)

We study thin films of homopolymers (PS) and monolayers of cylinder-forming diblock copolymers (PS–PHMA) under shear. To this end, we employed both experiments and computer simulations that correctly ...

Chelation-assisted substrate-controlled asymmetric lithiation-allylboration of chiral carbamate 1,2,4-butanetriol acetonide.

Molecules 20 , 9890-905, (2015)

The lithiation of 2-(2,2-dimethyl-1,3-dioxolan-4-yl)ethyl diisopropylcarbamate (1) is achieved freely by sec-butyllithium in diethylether with high lk-diastereoselectivity: the bicyclic chelate comple...

Membranes with artificial free-volume for biofuel production.

Nat. Commun. 6 , 7529, (2015)

Free-volume of polymers governs transport of penetrants through polymeric films. Control over free-volume is thus important for the development of better membranes for a wide variety of applications s...

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