1,6-己二胺盐酸盐
1,6-己二胺盐酸盐名称
[ CAS 号 ]:
6055-52-3
[ 中文名 ]:
1,6-己二胺盐酸盐
[ 英文名 ]:
1,6-Hexanediamine dihydrochloride
[中文别名 ]:
[英文别名 ]:
- hexane-1,6-diamine,dihydrochloride
- 1,6-Hexanediamine dihydrochloride
- 1,6-Hexanediamine, hydrochloride (1:2)
- Hexane-1,6-diamine dihydrochloride
- EINECS 227-977-8
- MFCD00012528
1,6-己二胺盐酸盐物理化学性质
[ 沸点 ]:
205ºC at 760 mmHg
[ 熔点 ]:
256-257 °C(lit.)
[ 分子式 ]:
C6H18Cl2N2
[ 分子量 ]:
189.126
[ 闪点 ]:
81.1ºC
[ 精确质量 ]:
188.084702
[ PSA ]:
52.04000
[ LogP ]:
3.46880
[ 外观性状 ]:
近乎于白色结晶粉末
[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (吸湿)
[ 水溶解性 ]:
水溶性:完全溶解
1,6-己二胺盐酸盐MSDS
1,6-己二胺盐酸盐毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- MO1312000
- CHEMICAL NAME :
- 1,6-Hexanediamine, dihydrochloride
- CAS REGISTRY NUMBER :
- 6055-52-3
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C6-H16-N2.2Cl-H
- MOLECULAR WEIGHT :
- 189.16
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3682 mg/kg/2W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight
- REFERENCE :
- NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-93-3347
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 50 mg/m3/6H/13W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes Blood - changes in leukocyte (WBC) count
- REFERENCE :
- FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 800 mg/m3/6H/2W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes Related to Chronic Data - death
- REFERENCE :
- FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 800 mg/m3/6H/2W-I
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Endocrine - changes in thymus weight Related to Chronic Data - death
- REFERENCE :
- FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 160 mg/m3/6H/13W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - changes in lung weight Liver - changes in liver weight
- REFERENCE :
- FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993
1,6-己二胺盐酸盐安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H315-H319-H335
[ 警示性声明 ]:
P261-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xi: Irritant;
[ 风险声明 (欧洲) ]:
R36/37/38
[ 安全声明 (欧洲) ]:
S26-S37/39
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
3
[ RTECS号 ]:
MO1312000
[ 海关编码 ]:
2921229000
1,6-己二胺盐酸盐合成路线
1,6-己二胺盐酸盐海关
[ 海关编码 ]: 2921229000
[ 中文概述 ]:
2921229000 六亚甲基二胺及其他盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2921229000 hexamethylenediamine and its salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
1,6-己二胺盐酸盐文献
Appl. Biochem. Biotechnol. 163(2) , 258-67, (2011)
Phenylalanine dehydrogenase (L-PheDH) from Sporosarcina ureae was immobilized on DEAE-cellulose, modified initially with 2-amino-4,6-dichloro-s-triazine followed by hexamethylenediamine and glutaralde...
Analysis of polyamines as carbamoyl derivatives in urine and serum by liquid chromatography-tandem mass spectrometry.Biomed. Chromatogr. 22(1) , 73-80, (2008)
A quantitative analysis of polyamines in urine and serum by liquid chromatography-tandem mass spectrometry (LC-MS/MS) is described. The polyamines were carbamylated with isobutyl chloroformate, extrac...
Receptor-based detection of 2,4-dinitrotoluene using modified three-dimensionally ordered macroporous carbon electrodes.ACS Appl. Mater. Interfaces 4(9) , 4731-9, (2012)
Detection of explosives, such as 2,4,6-trinitrotoluene (TNT), is becoming increasingly important. Here, 2,4-dinitrotoluene (DNT, a common analogue of TNT) is detected electrochemically. A receptor bas...
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