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|S|-(+)-3-氯-1,2-丙二醇

|S|-(+)-3-氯-1,2-丙二醇用途

【用途一】
用于合成手性试剂及医药中间体
【用途二】
1.药物中间体； 2.合成手性精细化学品中间体。

|S|-(+)-3-氯-1,2-丙二醇名称

[ CAS 号 ]:
60827-45-4

[ 中文名 ]:
(S)-3-氯-1,2-丙二醇

[ 英文名 ]:
(2S)-3-Chlorpropan-1,2-diol

[中文别名 ]:

[英文别名 ]:

(S)-3-Chloro-1,2-propanediol
1,2-Propanediol, 3-chloro-, (S)-
EINECS 202-492-4
Q1YQ1G &&S Form
(2S)-3-chloropropane-1,2-diol
(2S)-3-Chloro-1,2-propanediol
1,2-Propanediol, 3-chloro-, (2S)-
MFCD00210270
(2S)-3-Chlorpropan-1,2-diol
(S)-(+)-3-chloro-1,2-propanediol

|S|-(+)-3-氯-1,2-丙二醇物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
213.0±0.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₇ClO₂

[ 分子量 ]:
110.539

[ 闪点 ]:
113.3±21.8 °C

[ 精确质量 ]:
110.013458

[ PSA ]:
40.46000

[ LogP ]:
-0.76

[ 外观性状 ]:
透明黄色至橙色-黄色液体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.474

[ 储存条件 ]:
室温

[ 水溶解性 ]:
水溶性：完全混溶；易溶于：醇；不溶：乙醚

|S|-(+)-3-氯-1,2-丙二醇MSDS

|S|-(+)-3-氯-1,2-丙二醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TY4202300

CHEMICAL NAME :: 1,2-Propanediol, 3-chloro-, (S)-

CAS REGISTRY NUMBER :: 60827-45-4

LAST UPDATED :: 198910

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C3-H7-O2

MOLECULAR WEIGHT :: 75.10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 45500 ug/kg

SEX/DURATION :: male 14 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females)

REFERENCE :: JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 51,105,1977

|S|-(+)-3-氯-1,2-丙二醇安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H312-H318

[ 警示性声明 ]:
P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R21;R23/25;R36/37/38;R62;R68

[ 安全声明 (欧洲) ]:
S26-S28-S39-S45-S36/37/39

[ 危险品运输编码 ]:
UN 2689 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
TY4202300

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2905590090

|S|-(+)-3-氯-1,2-丙二醇合成路线

|S|-(+)-3-氯-1,2-丙二醇上下游产品

|S|-(+)-3-氯-1,2-丙二醇上游产品

|S|-(+)-3-氯-1,2-丙二醇下游产品

|S|-(+)-3-氯-1,2-丙二醇海关

[ 海关编码 ]: 2905590090

[ 中文概述 ]:
2905590090 其他无环醇的卤化、磺化等衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

|S|-(+)-3-氯-1,2-丙二醇文献

Complete detoxification of tris(1,3-dichloro-2-propyl) phosphate by mixed two bacteria, Sphingobium sp. strain TCM1 and Arthrobacter sp. strain PY1.

J. Biosci. Bioeng. 113(1) , 79-83, (2012)

Tris(1,3-dichloro-2-propyl) phosphate (TDCPP), a flame retardant, is regarded as a potentially toxic and persistent environmental contaminant. We previously isolated a TDCPP-degrading bacterium, Sphin...

Passage of MHPG from plasma to CSF in a non-human primate.

Rev. Med. Chir. Soc. Med. Nat. Iasi. 115(4) , 1278-82, (2011)

In experimental protocols with humans and non-human primates, cerebrospinal fluid (CSF) concentrations of 3-methoxy-4-hydroxyphenylethylene glycol (MHPG), the predominant end-product of norepinephrine...

Fatty acid esters of monochloropropanediol (MCPD) and glycidol in refined edible oils.

Food Addit. Contam. Part A. Chem. Anal. Control. Expo. Risk Assess. 30(1) , 46-51, (2013)

Recently, fatty acid esters of monochloropropanediol (MCPD) and that of glycidol have been reported in refined edible oils. Since then a wealth of research has been published on the factors influencin...

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