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3-甲碘苯

3-甲碘苯用途

【用途一】
主要用于生物制药
【用途二】
用于有机合成

3-甲碘苯名称

[ CAS 号 ]:
625-95-6

[ 中文名 ]:
3-碘甲苯

[ 英文名 ]:
3-Iodotoluene

[中文别名 ]:

[英文别名 ]:

3-methyliodobenzene
3-iodo-toluene
Toluene,m-iodo-(7CI,8CI)
Toluene,m-iodo
3-Methylphenyl iodide
EINECS 210-918-5
Benzene,1-iodo-3-methyl
3-Iodotoluene
Toluene, m-iodo-
m-Iodotoluene

3-甲碘苯物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
213.0±0.0 °C at 760 mmHg

[ 熔点 ]:
-27°C

[ 分子式 ]:
C₇H₇I

[ 分子量 ]:
218.035

[ 闪点 ]:
82.2±0.0 °C

[ 精确质量 ]:
217.959229

[ LogP ]:
3.71

[ 外观性状 ]:
略黄色液体

[ 蒸汽压 ]:
0.2±0.4 mmHg at 25°C

[ 折射率 ]:
1.605

[ 储存条件 ]:
室温，避光

3-甲碘苯MSDS

3-甲碘苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA3440000

CHEMICAL NAME :: Benzene, 1-iodo-3-methyl-

CAS REGISTRY NUMBER :: 625-95-6

BEILSTEIN REFERENCE NO. :: 1903634

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C7-H7-I

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2296 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 36(9-10),44,1992

3-甲碘苯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
UN 2810

[ WGK德国 ]:
2

[ RTECS号 ]:
DA3440000

[ 海关编码 ]:
2903999090

3-甲碘苯合成路线

3-甲碘苯上下游产品

3-甲碘苯上游产品

3-甲碘苯下游产品

3-甲碘苯海关

[ 海关编码 ]: 2903999090

[ 中文概述 ]:
2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

3-甲碘苯文献

Mizoroki-heck-type reaction mediated by potassium tert-butoxide.

Angew. Chem. Int. Ed. Engl. 50(20) , 4671-4, (2011)

Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds.

Org. Biomol. Chem. 6(6) , 1040-5, (2008)

The palladium-catalyzed carboannulation and arylation reaction of propargylic carbonates with in situ generated organozinc compounds produced an important new class of indene derivatives. The reaction...

[Information on basics of MAC for m-toluate iodide in the air of work area].

Gig. Tr. Prof. Zabol. (9-10) , 44-5, (1992)

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