乙酸亚汞

乙酸亚汞用途

1.用作分析试剂，也用于制药工业.

乙酸亚汞名称

[ CAS 号 ]:
631-60-7

[ 中文名 ]:
乙酸亚汞

[ 英文名 ]:
mercury(i) acetate

[中文别名 ]:

酯酸亞汞

[英文别名 ]:

mercury(1+),acetate
EINECS 211-161-3
MFCD00083002
Mercury(I) acetate

乙酸亚汞物理化学性质

[ 密度 ]:
3,27 g/cm3

[ 沸点 ]:
117.1ºC at 760 mmHg

[ 熔点 ]:
178-180°C

[ 分子式 ]:
C₄H₆Hg₂O₄

[ 分子量 ]:
519.26800

[ 闪点 ]:
210-220°C

[ 精确质量 ]:
521.96800

[ PSA ]:
52.60000

[ LogP ]:
0.02260

[ 折射率 ]:
1.303

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

乙酸亚汞MSDS

详细MSDS(安全技术说明书)

乙酸亚汞毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AI8570000

CHEMICAL NAME :: Acetic acid, mercury (1+) salt

CAS REGISTRY NUMBER :: 631-60-7

LAST UPDATED :: 199409

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C2-H3-O2.Hg

MOLECULAR WEIGHT :: 259.64

WISWESSER LINE NOTATION :: OV1 &-HG-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 175 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 960 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 150 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 10200 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 600 mg/kg/4W-I

REFERENCE :: TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 51,67,1988 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO MERCURY, ARYL AND INORGANIC-air:CL 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

乙酸亚汞安全信息

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
26/27/28-33-50/53

[ 安全声明 (欧洲) ]:
13-28-45

[ 危险品运输编码 ]:
1629

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

乙酸亚汞合成路线

详细合成路线

乙酸亚汞上下游产品

乙酸亚汞上游产品

乙酸亚汞下游产品

乙酸亚汞制备

1.将20g二水硝酸汞(Ⅰ)［Hg2(NO3)2·2H2O］溶于加有3.5g 25%硝酸的120mL水中。另取15g无水醋酸钠溶在50mL水中。在搅拌下，将此溶液加至上述已配制好的硝酸汞（Ⅰ）溶液中，醋酸汞（Ⅰ）沉淀析出。抽滤，用冷水洗涤，置于棕色保干器中避光干燥，收量为13g。

2. 将硝酸亚汞置于阴冷处，在稀硝酸的环境下加入乙酸钠生成沉淀，过滤洗涤后用氯化钙干燥即得：