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2-硝基-N'-(2-亚丙基)-苯磺酰肼

2-硝基-N'-(2-亚丙基)-苯磺酰肼名称

[ CAS 号 ]:
6655-27-2

[ 中文名 ]:
N'-异丙亚基-2-硝基苯磺酰

[ 英文名 ]:
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide

[中文别名 ]:

[英文别名 ]:

MFCD09800525
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide

2-硝基-N'-(2-亚丙基)-苯磺酰肼物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
421.3±47.0 °C at 760 mmHg

[ 熔点 ]:
131-135ºC

[ 分子式 ]:
C₉H₁₁N₃O₄S

[ 分子量 ]:
257.266

[ 闪点 ]:
208.6±29.3 °C

[ 精确质量 ]:
257.047028

[ PSA ]:
112.73000

[ LogP ]:
1.02

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.603

[ 储存条件 ]:
<0°C

2-硝基-N'-(2-亚丙基)-苯磺酰肼MSDS

2-硝基-N'-(2-亚丙基)-苯磺酰肼安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3.0

2-硝基-N'-(2-亚丙基)-苯磺酰肼合成路线

2-硝基-N'-(2-亚丙基)-苯磺酰肼上下游产品

2-硝基-N'-(2-亚丙基)-苯磺酰肼上游产品

2-硝基-N'-(2-亚丙基)-苯磺酰肼下游产品

2-硝基-N'-(2-亚丙基)-苯磺酰肼文献

N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.

J. Org. Chem. 72 , 1838, (2007)

The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates access...

A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.

Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)

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