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甲苯氟磺胺

甲苯氟磺胺用途

可防治苹果的黑星病，草莓和其他观赏植物的花腐病。制剂有50％可湿性粉剂。

甲苯氟磺胺名称

[ CAS 号 ]:
731-27-1

[ 中文名 ]:
甲苯氟磺胺

[ 英文名 ]:
dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide

[中文别名 ]:

甲抑菌灵

[英文别名 ]:

Tolyfluanide
Tolylfluanide [ISO-French]
tolilfluanide
Dichlofluanid-methyl
TOLYLFLUANID
Tolylfluanide
MFCD00055477
Euparen M
Tolylfluanid [BSI:ISO]
Bayer 5712a

甲苯氟磺胺物理化学性质

[ 密度 ]:
1.505g/cm3

[ 沸点 ]:
366ºC at 760 mmHg

[ 熔点 ]:
96°C

[ 分子式 ]:
C₁₀H₁₃Cl₂FN₂O₂S₂

[ 分子量 ]:
347.25700

[ 闪点 ]:
175.1ºC

[ 精确质量 ]:
345.97800

[ PSA ]:
74.30000

[ LogP ]:
4.39520

[ 折射率 ]:
1.606

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

甲苯氟磺胺MSDS

详细MSDS(安全技术说明书)

甲苯氟磺胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WO6560000

CHEMICAL NAME :: Sulfamide, N-((dichlorofluoromethyl)thio)-N',N'-dimethyl-N-(p-to lyl)-

CAS REGISTRY NUMBER :: 731-27-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C10-H13-Cl2-F-N2-O2-S2

MOLECULAR WEIGHT :: 347.27

WISWESSER LINE NOTATION :: GXGFSNR D1&SWN1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,505,1973

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 300 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,827,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,505,1973

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PSSCBG Pesticide Science. (Blackwell Scientific Pub. Ltd., POB 88, Oxford, UK) V.1- 1970- Volume(issue)/page/year: 4,-,1973

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PSSCBG Pesticide Science. (Blackwell Scientific Pub. Ltd., POB 88, Oxford, UK) V.1- 1970- Volume(issue)/page/year: 4,-,1973

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,225,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C131,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,225,1976

甲苯氟磺胺安全信息

[ 符号 ]:

GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H315-H317-H319-H330-H335-H372-H400

[ 警示性声明 ]:
P260-P273-P280-P284-P305 + P351 + P338-P310

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T,N

[ 风险声明 (欧洲) ]:
23-36/37/38-43-48/20-50/53

[ 安全声明 (欧洲) ]:
S24;S26;S37;S38;S45;S60;S61

[ 危险品运输编码 ]:
UN 2588

[ RTECS号 ]:
WO6560000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

甲苯氟磺胺上下游产品

甲苯氟磺胺上游产品

甲苯氟磺胺下游产品

甲苯氟磺胺制备

由Cl₃CSCl与HF反应，生成物再与N-对甲苯胺-N′,N′-二甲基磺酰胺反应，即制得本品。

甲苯氟磺胺文献

Baby food production chain: pesticide residues in fresh apples and products.

Food Addit. Contam. 22(12) , 1231-42, (2005)

During 3 years of a monitoring programme, 522 samples of fresh apples, six brands of fruit purées and various types of fruit baby food prepared from these materials were analysed. Each sample was exam...

[Occurrence of pesticide residues in raspberries in 2000-2005].

Rocz. Panstw. Zakl. Hig. 58(3) , 509-13, (2007)

The aim of this paper was to present occurrence of pesticide residues in raspberries in 2000-2005. Gas chromatographic and spectroscopy methods were used. The most frequently found were tolylfluanid r...

Exposure to fungicides in fruit growing: re-entry time as a predictor for dermal exposure.

Am. Ind. Hyg. Assoc. J. 60(6) , 789-93, (1999)

As part of a European Concerted Action on Male Reproduction Capability an exposure assessment survey was conducted among seasonal workers in the fruit growing sector in the Netherlands. Dermal exposur...

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