乙炔
乙炔用途
用途二:广泛用于金属焊接和气源切割,同时还可用于医药加工、仪器分析和有机合成等领域
用途三:乙炔在高温下分解为碳和氢,由此可制备乙炔炭黑。一定条件下乙炔聚合生成苯,甲苯,二甲苯,,萘,蒽,苯乙烯,茚等芳烃。通过取代反应和加成反应,可生成一系列极有价值的产品。例如乙炔二聚生成乙烯基乙炔,进而与氯化氢进行加成反应得到氯丁二烯;乙炔直接水合制取乙醛;乙炔与氯化氢进行加成反应而制取氯乙烯;乙炔与乙酸反应制得乙酸乙烯;乙炔与氰化氢反应制取丙烯腈;乙炔与氨反应生成甲基吡啶和2-甲基-5-乙基吡啶;乙炔与甲苯反应生成二甲笨基乙烯,进一步催化剂裂化生成三种甲基苯乙烯的异构体:乙炔与一分子甲醛缩合为丙炔醇,与二分子甲醛缩合为丁炔二醇;乙炔与丙酮进行加成反应可制取甲基炔醇,进而反应生成异戊二烯;乙炔和一氧化碳及其他化合物(如水,醇,硫醇)等反应制取丙烯酸及其衍生物。
乙炔名称
[ CAS 号 ]:
74-86-2
[ 中文名 ]:
乙炔
[ 英文名 ]:
Acetylene
[中文别名 ]:
[英文别名 ]:
- Welding Gas
- MFCD00008567
- 4-01-00-00939
- Ethyne
- C2H2
- Ethine
- vinylene
- Acetylen
- EINECS 200-816-9
- ethenylene
乙炔物理化学性质
[ 密度 ]:
0.6±0.1 g/cm3
[ 沸点 ]:
-28 ºC
[ 熔点 ]:
-88°C
[ 分子式 ]:
C2H2
[ 分子量 ]:
26.037
[ 闪点 ]:
-18 ºC
[ 精确质量 ]:
26.015650
[ LogP ]:
0.37
[ 外观性状 ]:
一种无色气体带有一种微弱像大蒜一样的气味
[ 蒸汽压 ]:
69690.6±0.1 mmHg at 25°C
[ 折射率 ]:
1.316
[ 储存条件 ]:
库房通风低温干燥,轻装轻卸,与氧气、空气、氯气气体钢瓶分开存放
[ 水溶解性 ]:
0.106 g/100 mL
乙炔MSDS
乙炔毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AO9600000
- CHEMICAL NAME :
- Acetylene
- CAS REGISTRY NUMBER :
- 74-86-2
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 22
- MOLECULAR FORMULA :
- C2-H2
- MOLECULAR WEIGHT :
- 26.04
- WISWESSER LINE NOTATION :
- 1UU1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 20 pph
- TOXIC EFFECTS :
- Behavioral - headache Lungs, Thorax, or Respiration - dyspnea
- REFERENCE :
- 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,67,1969
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 50 pph/5M
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TABIA2 Tabulae Biologicae. (The Hague, Netherlands) V.1-22, 1925-63. Discontinued. Volume(issue)/page/year: 3,231,1933
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 50 pph/5M
- REFERENCE :
- AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 138,65,1928 *** REVIEWS *** ACGIH TLV-Simple asphyxiant, NO TWA DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD:ASPHYXIANTS/GASES DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,8,1973 OSHA PEL (Construc):simple asphyxiant - inert gas and vapor CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):Simple asphyxiant - inert gas and vapor CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):Simple asphyxiant - inert gas and vapor CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 1 ppm (14 mg/m3) JAN 1993 OEL-AUSTRALIA:Asphyxiant JAN 1993 OEL-BELGIUM:Asphyxiant JAN 1993 OEL-HUNGARY:Asphyxiant JAN 1993 OEL-THE NETHERLANDS:Asphyxiant JAN 1993 OEL-SWITZERLAND:TWA 1000 ppm (1080 mg/m3) JAN 1993 OEL-UNITED KINGDOM:Asphyxiant JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ACETYLENE-air:CL 2500 ppm/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 03298 No. of Facilities: 85909 (estimated) No. of Industries: 341 No. of Occupations: 111 No. of Employees: 704679 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 03298 No. of Facilities: 2514 (estimated) No. of Industries: 41 No. of Occupations: 52 No. of Employees: 48962 (estimated) No. of Female Employees: 3072 (estimated)
乙炔安全信息
[ 危害码 (欧洲) ]:
F+:Highlyflammable;
[ 风险声明 (欧洲) ]:
R5
[ 安全声明 (欧洲) ]:
S9-S16-S33
[ 危险品运输编码 ]:
UN 1001
[ 危险类别 ]:
2.1
[ 海关编码 ]:
2901292000
乙炔上下游产品
乙炔上游产品
乙炔下游产品
乙炔制备
1.电石法:由电石(碳化钙)与水作用得到乙炔。
2.天然气制乙炔法:预热到600~650℃的原料天然气和氧进入多管式烧嘴板乙炔炉,在1500℃下,甲烷裂解制得8%左右的稀乙炔,再用犖甲基吡咯烷酮提浓制得99%的乙炔成品。
乙炔海关
[ 海关编码 ]: 2901292000
[ 中文概述 ]:
2901292000 乙炔。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最低关税:2.0%。普通关税:45.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 用作气体燃料的应报明包装容器容积, 散装货物应报明
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: M.进口商品检验 N.出口商品检验
[ Summary ]:
2901292000 ethyne。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:2.0%。general tariff:45.0%
相关化工产品/化学物质:
推荐生产厂家/供应商:
乙炔相关知识
2019-07-10 16:50:23
乙炔(acetylene)最简单的炔烃,又称电石气。分子式CH≡CH,是最简单的炔烃,化学式C2H2,分子结构:C原子以sp杂化轨道成键、分子为直线形的非极性分子。无色有芳香气味的易燃气体。熔点-80.8℃,沸点-84℃,相对密度0.6208(-82/4℃)。在液态和固态下或在气态和一定压力下有猛...
相关化合物
【乙炔】化源网提供乙炔CAS号74-86-2,乙炔MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询乙炔上化源网,专业又轻松。>>电脑版:乙炔
标题:乙炔_MSDS_用途_密度_乙炔CAS号【74-86-2】_化源网 地址:https://www.chemsrc.com/amp/cas/74-86-2_749651.html