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钨粉

钨粉用途

【用途一】
用作分析试剂
【用途二】
用于制造硬质或耐高温合金、高速切削特种钢,以及用作灯泡灯丝和航空、航天工业的耐热材料
【用途三】
FW-1用于大型板坯、钨铼电偶原料。FW-2用于触头合金、高比重屏蔽原料。FWP-1用等离子喷镀材料。
【用途四】
大型板坯、钨铼热电偶原料(FW1),触头合金、高密度屏蔽材料(FW2)。
【用途五】
用于制钨丝和制高速切削钢、特种钢等, 也用于制电学仪器和光学仪器。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。

钨粉名称

[ CAS 号 ]:
7440-33-7

[ 中文名 ]:

[ 英文名 ]:
Tungsten

[中文别名 ]:

[英文别名 ]:

钨粉物理化学性质

[ 密度 ]:
19.3

[ 沸点 ]:
5660ºC

[ 熔点 ]:
3410ºC

[ 分子式 ]:
W

[ 分子量 ]:
183.84000

[ 闪点 ]:
-23ºC

[ 精确质量 ]:
183.95100

[ 外观性状 ]:
金属丝

[ 储存条件 ]:
库房通风低温干燥,包装密闭

[ 稳定性 ]:
Stable. Dust is flammable, though not likely to present a hazard if normal good practice is used.

[ 水溶解性 ]:
insoluble

钨粉MSDS

钨粉毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YO7175000
CHEMICAL NAME :
Tungsten
CAS REGISTRY NUMBER :
7440-33-7
LAST UPDATED :
199710
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
W
MOLECULAR WEIGHT :
183.85
WISWESSER LINE NOTATION :
WO

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,19,1972
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,19,1972 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Vascular - regional or general arteriolar or venous dilation Liver - other changes Blood - other changes
REFERENCE :
INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 15,482,1946 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1210 ug/kg
SEX/DURATION :
female 35 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 42(8),30,1977
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1160 ug/kg
SEX/DURATION :
female 30 week(s) pre-mating female 1-20 day(s) after conception
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 41,620,1978 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg/m3 (soluble) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,272,1971 MSHA STANDARD:air-TWA 5 mg/m3 (insoluble) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,272,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 5 mg/m3 JAN 1993 OEL-RUSSIA:STEL 2 mg/m3 JAN 1993 OEL-SWEDEN:TWA 5 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg/m3;STEL 10 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TUNGSTEN, insoluble-air:TWA 5 mg(W)/m3;STEL 10 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TUNGSTEN, soluble-air:10H TWA 1 mg(W)/m3;STEL 3 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 74980 No. of Facilities: 530 (estimated) No. of Industries: 20 No. of Occupations: 24 No. of Employees: 4735 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5928 No. of Facilities: 53 (estimated) No. of Industries: 4 No. of Occupations: 11 No. of Employees: 3907 (estimated) No. of Female Employees: 1258 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7685 No. of Facilities: 174 (estimated) No. of Industries: 5 No. of Occupations: 15 No. of Employees: 4822 (estimated) No. of Female Employees: 3021 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 74980 No. of Facilities: 1623 (estimated) No. of Industries: 52 No. of Occupations: 43 No. of Employees: 38323 (estimated) No. of Female Employees: 3591 (estimated)

钨粉安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H228-H315-H319

[ 警示性声明 ]:
P210-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R11;R36/38

[ 安全声明 (欧洲) ]:
S6-S26-S36

[ 危险品运输编码 ]:
UN 3089

[ WGK德国 ]:
-

[ RTECS号 ]:
YO7175000

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

钨粉合成路线

钨粉上下游产品

钨粉制备

1.钨的主要矿物有黑钨矿、白钨矿,中国储量居世界首位。可由碱处理黑钨矿制得三氧化钨后,再用氢气还原制取金属钨。电解制取钨可采用卤化物、磷酸盐、硼酸盐等多种电解质体系,可用钨的氧化物、卤化物等形式作为原料加入熔体。工业生产可用氢气还原三氧化钨制得;或将仲钨酸铵用酸处理,再经热分解得到三氧化钨,用氢气还原制得。
氢气还原三氧化钨法用氢气还原可分二个阶段进行,第一阶段将三氧化钨加热至450~600℃,用氢气还原,第二阶段还原在750~1100℃时进行,制得钨粉成品。其

2.钨的主要矿石有黑钨矿(Fe、Mn)WO4及白钨矿CaWO4。以黑钨矿为原料时,在矿石中加入碳酸钠及少量氯化钠或氟化钠,在800~1000℃熔融,使其生成钨酸钠,用水抽提。或者用浓氢氧化钠水溶液在加压下或在101325Pa压力下煮沸,以钨酸钠形式抽提出来。以白钨矿作原料时,用盐酸分解可以析出钨酸。调节溶液的pH值,可以除去用上述方法得到的钨酸钠溶液中所含的硅。利用添加氯化镁、氯化铵溶液的方法除去磷和砷,对于钼,可以利用添加硫化钠使之成为硫化物而除去。进一步提纯时,可在钨酸钠溶液中加入氯化钙,生成钨酸钙沉淀析出,在沉淀中加入盐酸使其析出钨酸,将钨酸溶于氨水中,然后加热浓缩或中和而析出仲钨酸铵。钨粉可由精制仲钨酸铵直接用氢还原制得;或者将仲钨酸铵用酸处理或热分解制得三氧化钨,再用氢还原来制取。一般情况下,用氢还原可分两、三个阶段进行。例如,第一阶段还原在450~600℃,第二阶段还原在750~1100℃时进行。

钨粉文献

Effect of particle size of PtRu nanoparticles embedded in WO3 on electrocatalysis.

J. Nanosci. Nanotechnol. 13(5) , 3591-6, (2013)

Size-controlled PtRu nanoparticles embedded in WO3 were prepared by simultaneous multigun sputtering on pure targets of Pt, Ru, and WO3. The mean diameter of the PtRu nanoparticles, as confirmed by hi...

Diagnostic use of cerebral and extracerebral oxysterols.

Clin. Chem. Lab Med. 42(2) , 186-91, (2004)

24S-Hydroxycholesterol (24OHC) and 27-hydroxycholesterol (27OHC) are two structurally similar oxysterols of different origins--the former almost exclusively formed in the brain and the latter formed t...

Levels of 7-oxocholesterol in cerebrospinal fluid are more than one thousand times lower than reported in multiple sclerosis.

J. Lipid Res. 46(2) , 191-5, (2005)

In a recent publication [Diestel, A., O. Aktas, D. Hackel, I. Hake, S. Meier, C. S. Raine, R. Nitsch, F. Zipp, and O. Ullrich. 2003. Activation of microglial poly (ADP-ribose)-polymerase-1 by choleste...


更多文献

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公司名:上海化源世纪贸易有限公司

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价格:

联系人:徐经理

产品详情:钨标准溶液


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价格:
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公司名:上海阿拉丁生化科技股份有限公司

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公司名:上海创赛科技有限公司

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¥2930.0/2500g ¥257.0/100g ¥790.0/500g ¥81.0/25g

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产品详情:[Perfemiker]钨粉,99.5% metals basis,25μm


公司名:武汉敬康恩生物医药科技有限公司

区域:武汉市东西湖区

价格:
¥需询单/1g

联系人:周经理

产品详情:Tungsten


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相关化合物

【钨粉】化源网提供钨粉CAS号7440-33-7,钨粉MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询钨粉上化源网,专业又轻松。>>电脑版:钨粉

标题:钨粉_MSDS_用途_密度_钨粉CAS号【7440-33-7】_化源网 地址:https://www.chemsrc.com/amp/cas/7440-33-7_965728.html