草酸亚锡
草酸亚锡用途
用作织物印染剂和煤的气化催化剂
【用途二】
酯化反应催化剂。煤的氢化催化剂。蓝图印纸的晒制。
草酸亚锡名称
[ CAS 号 ]:
814-94-8
[ 中文名 ]:
草酸亚锡
[ 英文名 ]:
Stannous oxalate
[中文别名 ]:
[英文别名 ]:
- TERBIUM(III) OXALATE HYDRATE,99.
- tin oxalate
- TERBIUM (III) OXALATE,HYDROUS
- oxalic acid,tin (IV)-compound
- EINECS 212-414-0
- TERBIUM OXALATE HYDRATE
- TERBIUM OXALATE
- TERBIUM(III) OXALATE HYDRATE
- oxalic acid,diterbium (III)-compound
- Oxalsaeure,Zinn(IV)-Verbindung
草酸亚锡物理化学性质
[ 密度 ]:
3.56 g/cm3
[ 沸点 ]:
365.1ºC at 760 mmHg
[ 熔点 ]:
280ºC
[ 分子式 ]:
C2O4Sn
[ 分子量 ]:
206.72000
[ 闪点 ]:
188.8ºC
[ 精确质量 ]:
207.88200
[ PSA ]:
80.26000
[ 外观性状 ]:
自由流动白色粉末
[ 储存条件 ]:
室温,惰性气体氛围
草酸亚锡MSDS
草酸亚锡毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XQ3950000
- CHEMICAL NAME :
- Tin(II) oxalate
- CAS REGISTRY NUMBER :
- 814-94-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 27
- MOLECULAR FORMULA :
- C2-H2-O4.Sn
- MOLECULAR WEIGHT :
- 208.73
- WISWESSER LINE NOTATION :
- OVVO &-SN-
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3620 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- MarJV# Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice, Czechoslavakia, Mar. 29, 1977 Volume(issue)/page/year: 29MAR1977
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - other changes Kidney, Ureter, Bladder - other changes
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570737 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 8863 mg/kg/4W-C
- TOXIC EFFECTS :
- Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - changes in iron
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2A,1946,1981
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 28806 mg/kg/13W-C
- TOXIC EFFECTS :
- Behavioral - food intake (animal) Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2A,1946,1981 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,257,1971 OSHA PEL (Gen Indu):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Sn)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Sn)/m3 JAN 1993 OEL-FINLAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 2 mg(Sn)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2 mg(Sn)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 JAN 1993 OEL-THAILAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83516 No. of Facilities: 8 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 88 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83516 No. of Facilities: 72 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 2953 (estimated) No. of Female Employees: 504 (estimated)
草酸亚锡安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H312
[ 警示性声明 ]:
P280
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful;
[ 风险声明 (欧洲) ]:
R21/22
[ 安全声明 (欧洲) ]:
S24/25
[ 危险品运输编码 ]:
UN 3288
[ WGK德国 ]:
1
[ RTECS号 ]:
XQ3950000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
[ 海关编码 ]:
29171100
草酸亚锡合成路线
草酸亚锡上下游产品
草酸亚锡上游产品
草酸亚锡下游产品
草酸亚锡海关
[ 海关编码 ]: 29171100
草酸亚锡文献
Sci. Rep. 6 , 23915, (2016)
A commercially applicable and simple process for the preparation of aggregation-free metal oxide hollow nanospheres is developed by applying nanoscale Kirkendall diffusion to a large-scale spray dryin...
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