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1-Boc-四氢吡咯

1-Boc-四氢吡咯名称

[ CAS 号 ]:
86953-79-9

[ 中文名 ]:
1-Boc-四氢吡咯

[ 英文名 ]:
2-Methyl-2-propanyl 1-pyrrolidinecarboxylate

[中文别名 ]:

[英文别名 ]:

tert-butyl pyrrolidine-1-carboxylate
MFCD00216581

1-Boc-四氢吡咯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
221.4±9.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₇NO₂

[ 分子量 ]:
171.237

[ 闪点 ]:
87.7±18.7 °C

[ 精确质量 ]:
171.125931

[ PSA ]:
29.54000

[ LogP ]:
1.49

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.473

[ 储存条件 ]:
存放于惰性气体之中;避免空气

1-Boc-四氢吡咯MSDS

1-Boc-四氢吡咯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NA 1993 / PGIII

[ WGK德国 ]:
3

[ 海关编码 ]:
2933990090

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1-Boc-四氢吡咯海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-Boc-四氢吡咯文献

Enantioselective, palladium-catalyzed α-arylation of N-Boc pyrrolidine: in situ react IR spectroscopic monitoring, scope, and synthetic applications.

J. Org. Chem. 76(15) , 5936-53, (2011)

A comprehensive study of the enantioselective Pd-catalyzed α-arylation of N-Boc pyrrolidine has been carried out. The protocol involves deprotonation of N-Boc pyrrolidine using s-BuLi/(-)-sparteine in...

Asymmetric synthesis of enantioenriched (+)-elaeokanine A.

J. Org. Chem. 71(15) , 5674-8, (2006)

The key transformation in the total synthesis of (+)-elaeokanine A was accomplished by asymmetric deprotonation of N-Boc pyrrolidine, followed by the reaction of the in situ generated enantioenriched ...

Enantioselective, palladium-catalyzed α-arylation of N-boc-pyrrolidine. Campos KR, et al.

J. Am. Chem. Soc. 128(11) , 3538-3539, (2006)

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