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Grubbs3代催化剂

Grubbs3代催化剂名称

[ CAS 号 ]:
900169-53-1

[ 中文名 ]:
[1,3-双均三甲苯基-2-咪唑烷亚基]二氯(苯基亚甲基)双(3-溴吡啶)钌(II)

[ 英文名 ]:
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II)

[中文别名 ]:

[英文别名 ]:

Grubbs3代催化剂物理化学性质

[ 分子式 ]:
C₃₈H₄₁Br₂Cl₂N₄Ru

[ 分子量 ]:
885.543

[ 精确质量 ]:
883.011902

[ PSA ]:
32.26000

[ LogP ]:
4.32880

[ 外观性状 ]:
绿色，粉末和/或块状

[ 储存条件 ]:
2-8°C

Grubbs3代催化剂MSDS

详细MSDS(安全技术说明书)

Grubbs3代催化剂安全信息

[ 危险品运输编码 ]:
NONH for all modes of transport

Grubbs3代催化剂文献

Use of olefin cross-metathesis to release azide-containing sugars from solid support.

Org. Lett. 5 , 4541, (2003)

[reaction: see text] The octenediol linker used during automated oligosaccharide assembly is cleaved by olefin cross-metathesis. Until now, this linker could not be applied to sugars containing azides...

A practical and highly active ruthenium-based catalyst that effects the cross metathesis of acrylonitrile.

Angew. Chem. Int. Ed. Engl. 41 , 4035, (2002)

Schrodi, Y.; Pederson, R.L.

Aldrichimica Acta 40 , 45, (2007)

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