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2-三氟甲基吩噻嗪

2-三氟甲基吩噻嗪用途

三氟拉嗪、氟奋乃静的中间体。

2-三氟甲基吩噻嗪名称

[ CAS 号 ]:
92-30-8

[ 中文名 ]:
2-三氟甲基吩噻嗪

[ 英文名 ]:
2-(Triflouomethyl) phenothiazine

[中文别名 ]:

[英文别名 ]:

Phenothiazine, 2- (trifluoromethyl)-
EINECS 202-145-7
2-(Trifluoromethyl)-10H-phenothiazine
10H-Phenothiazine, 2-(trifluoromethyl)-
2-(Triflouomethyl) phenothiazine
MFCD00005018
10H-Phenothiazine, 2- (trifluoromethyl)-

2-三氟甲基吩噻嗪物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
361.1±42.0 °C at 760 mmHg

[ 熔点 ]:
188-190 °C(lit.)

[ 分子式 ]:
C₁₃H₈F₃NS

[ 分子量 ]:
267.270

[ 闪点 ]:
172.2±27.9 °C

[ 精确质量 ]:
267.032959

[ PSA ]:
37.33000

[ LogP ]:
5.50

[ 外观性状 ]:
灰白色晶体

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.588

[ 储存条件 ]:
2-8°C

2-三氟甲基吩噻嗪MSDS

2-三氟甲基吩噻嗪毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SP5620000

CHEMICAL NAME :: Phenothiazine, 2-(trifluoromethyl)-

CAS REGISTRY NUMBER :: 92-30-8

BEILSTEIN REFERENCE NO. :: 0226580

LAST UPDATED :: 199712

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C13-H8-F3-N-S

MOLECULAR WEIGHT :: 267.28

WISWESSER LINE NOTATION :: T C666 BM ISJ EXFFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 520 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - rigidity (including catalepsy) Behavioral - muscle contraction or spasticity

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 12,110,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 32 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#07426

2-三氟甲基吩噻嗪安全信息

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S36

[ WGK德国 ]:
3

[ RTECS号 ]:
SP5620000

[ 海关编码 ]:
2934300000

2-三氟甲基吩噻嗪合成路线

2-三氟甲基吩噻嗪上下游产品

2-三氟甲基吩噻嗪上游产品

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2-三氟甲基吩噻嗪制备

用2-羧基-3-（三氟甲基）二苯胺（即合成抗菌剂氟灭酸）经高温催化脱羧（200℃ ，铁粉），生成3-（三氟甲基）二苯胺。将后者在碘参与下与硫黄一起加热，环合后制得该品。

2-三氟甲基吩噻嗪海关

[ 海关编码 ]: 2934300000

[ 中文概述 ]:
2934300000. 含一个吩噻嗪环系的化合物(吩噻嗪环系不论是否氢化,化合物未经进一步稠合的 ). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2934300000. other compounds containing in the structure a phenothiazine ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%