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反式-2-苯基环丙烷-羧酸

反式-2-苯基环丙烷-羧酸名称

[ CAS 号 ]:
939-90-2

[ 中文名 ]:
反式-2-苯基环丙烷-1-羧酸

[ 英文名 ]:
2-Phenylcyclopropanecarboxylic acid

[中文别名 ]:

[英文别名 ]:

1,2-Cyclohexanediol,monoacetate,cis
1-acetoxy-cyclohexan-2-ol
trans-2-acetoxy-1-cyclohexanol
(R,R)-2-acetoxycyclohexan-1-ol
UNII:AJY6BGY81V
(R,R)-1-acetoxycyclohexan-2-ol
Cyclopropanecarboxylic acid, 2-phenyl-, (1R,2R)-
trans-2-phenyl-1-cyclopropanecarboxylic acid
2-Phenylcyclopropanecarboxylic acid
MFCD00001292

反式-2-苯基环丙烷-羧酸物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
317.1±31.0 °C at 760 mmHg

[ 熔点 ]:
86-88 °C(lit.)

[ 分子式 ]:
C₁₀H₁₀O₂

[ 分子量 ]:
162.185

[ 闪点 ]:
144.3±19.5 °C

[ 精确质量 ]:
162.068085

[ PSA ]:
37.30000

[ LogP ]:
1.73

[ 外观性状 ]:
白色至米色结晶粉末

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.600

[ 储存条件 ]:
室温，干燥

反式-2-苯基环丙烷-羧酸MSDS

反式-2-苯基环丙烷-羧酸安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2916399090

反式-2-苯基环丙烷-羧酸合成路线

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反式-2-苯基环丙烷-羧酸海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

反式-2-苯基环丙烷-羧酸文献

Efficient syntheses of four stable-isotope labeled (1R)-menthyl (1S,2S)-(+)-2-phenylcyclopropanecarboxylates.

Org. Biomol. Chem. 4(14) , 2777-84, (2006)

Many carbenoid cyclopropanation reactions promoted by chiral catalysts give product mixtures reflecting impressive diastereo- and enantioselectivities. Few provide a single chiral product efficiently....

Hydrogen bonding and ring asymmetry in a substituted cyclopropane: (+)-trans-(1S,2S)-2-phenylcyclopropanecarboxylic acid at 208 K.

Acta Crystallogr. C 53 ( Pt 9) , 1280-2, (1997)

The title compound, C10H10O2, crystallized in space group P2(1) with two molecules in the asymmetric unit. In this structure, hydrogen bonding of the cyclic dimer type [with O ... O 2.623(2)-2.637(2)A...

Hydrogen bonding and ring asymmetry in (+/-)-cis-2-phenylcyclopropanecarboxylic acid.

Acta Crystallogr. C 53 ( Pt 12) , 1989-91, (1997)

The title compound, (+/-)-cis-2-phenylcyclopropanecarboxylic acid, C10H10O2, crystallized in the centrosymmetric space group P2(1)/n. The hydrogen bonding is of the cyclic dimer type about a center of...

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