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1,1'-双(二-叔丁基膦基)二茂铁二氯合钯

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯用途

化学试剂

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯名称

[ CAS 号 ]:
95408-45-0

[ 中文名 ]:
[1,1'-二(二叔丁基膦)二茂铁]合二氯钯(II)

[ 英文名 ]:
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

[中文别名 ]:

[英文别名 ]:

MFCD08064219

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯物理化学性质

[ 熔点 ]:
203-208ºC

[ 分子式 ]:
C₂₆H₄₄Cl₂FeP₂Pd

[ 分子量 ]:
651.746

[ 精确质量 ]:
650.067932

[ PSA ]:
27.18000

[ LogP ]:
9.65990

[ 外观性状 ]:
crystal | dark purple

[ 储存条件 ]:
?20°C

[ 水溶解性 ]:
Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯MSDS

详细MSDS(安全技术说明书)

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 安全声明 (欧洲) ]:
24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
28439000

1,1'-双(二-叔丁基膦基)二茂铁二氯合钯文献

Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.

Org. Lett. 10 , 1333, (2008)

Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including st...

Cp2Fe(PR2)2PdCl2 (R = i-Pr, t-Bu) complexes as air-stable catalysts for challenging Suzuki coupling reactions.

Org. Lett. 6 , 3731, (2004)

[reaction: see text] The use of Cp(2)Fe(PR(2))(2)PdCl(2) (R = i-Pr and t-Bu) in Suzuki coupling reactions were illustrated using a high throughput screening approach. The di-tbpfPdCl(2) catalyst was s...

Heck couplings at room temperature in nanometer aqueous micelles.

Org. Lett. 10 , 1329, (2008)

A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. Th...

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