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硫线磷

硫线磷用途

Cadusafos is an organophosphorous-nematicide soil insecticide.

硫线磷名称

[ CAS 号 ]:
95465-99-9

[ 中文名 ]:
硫线磷

[ 英文名 ]:
cadusafos

[中文别名 ]:

[英文别名 ]:

Rugby
O-Ethyl S,S-bis(1-methylpropyl) phosphorodithioate
S,S-di(butan-2-yl) O-ethyl phosphorodithioate
ebufos
Toredan
O-Ethyl S,S-Bis(1-methylpropyl)phosphorodithioate
Apache
codusafos
2Y1&SPO&O2&SY2&1
S,S-Dibutan-2-yl O-ethyl phosphorodithioate

硫线磷物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
332.2±25.0 °C at 760 mmHg

[ 分子式 ]:
C₁₀H₂₃O₂PS₂

[ 分子量 ]:
270.392

[ 闪点 ]:
154.7±23.2 °C

[ 精确质量 ]:
270.087708

[ PSA ]:
86.71000

[ LogP ]:
4.28

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.489

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

硫线磷MSDS

详细MSDS(安全技术说明书)

硫线磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TE3800000

CHEMICAL NAME :: Phosphorodithioic acid, O-ethyl-, S,S-bis(1-methylpropyl)ester

CAS REGISTRY NUMBER :: 95465-99-9

LAST UPDATED :: 199712

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C10-H23-O2-P-S2

MOLECULAR WEIGHT :: 270.42

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 37100 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 32 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 71400 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 24400 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Ocular

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0539711

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 16 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: 230 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,114,1991

硫线磷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300 + H310 + H330-H400

[ 警示性声明 ]:
P260-P264-P273-P280-P284-P301 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T+

[ 风险声明 (欧洲) ]:
25-26-27-50/53

[ 安全声明 (欧洲) ]:
28-36/37-45-60-61

[ 危险品运输编码 ]:
UN 3018

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

硫线磷制备

1.O-乙基磷酰二氯的制备三氯氧磷与乙醇作用制得O-乙基磷酰二氯。硫线磷的合成 O-乙基磷酰二氯与1-甲基丙硫醇在缚酸剂存在下合成硫线磷。

2.由三氯氧磷与乙醇作用制得O-乙基磷酰二氯，然后在缚酸剂存在下与1-甲基丙硫醇反应得到硫线磷。

硫线磷文献

Interrogation of the Substrate Profile and Catalytic Properties of the Phosphotriesterase from Sphingobium sp. Strain TCM1: An Enzyme Capable of Hydrolyzing Organophosphate Flame Retardants and Plasticizers.

Biochemistry 54 , 7539-49, (2015)

The most familiar organophosphorus compounds are the neurotoxic insecticides and nerve agents. A related group of organophosphorus compounds, the phosphotriester plasticizers and flame retardants, has...

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硫线磷