1173021-83-4

• 常用中文名：ethyl 2,3,5,6-tetradeuterio-4-phenylpiperidine-4-carboxylate
• 常用英文名：ethyl 2,3,5,6-tetradeuterio-4-phenylpiperidine-4-carboxylate
• CAS号：1173021-83-4
• 分子式：C₁₄H₁₉NO₂
• 分子量：233.30600
• 发布时间：2016-06-21 07:41:35
• 更新时间：2024-02-25 23:08:18

名称

• 英文名: ethyl 2,3,5,6-tetradeuterio-4-phenylpiperidine-4-carboxylate
• 英文别名: Normeperidine-piperidine-d4 solution; Normeperidine-d4 solution

物化性质

• 分子式: C₁₄H₁₉NO₂
• 分子量: 233.30600
• 精确质量: 233.14200
• PSA: 38.33000
• LogP: 2.19970

MSDS

Version 1.1 Regulation (EC) No 1907/2006 1 - Product and Company Information Product NameNORMEPERIDINE-D4 (1MG/ML METHANOL SOLN) 99% 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number NORMEPERIDINE (1MG/ML METHANOLNoneNoneNone SOLN) Ingredient NamePercent CAS #EC noAnnex I Index Number METHANOL99.967-56-1200-659-6 603-001-00-X Symbols: F-T R-Phrases: 11-23/24/25-39/23/24/25 Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. 4-PHENYL-4-PIPERIDINECARB0.1NoneNoneNone OXYLIC ACID ETHYL ESTER Symbols: Xn R-Phrases: 22 Harmful if swallowed. 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. FLUKAwww.molbase.com AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. 5 - Fire Fighting Measures EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Flammable liquid. Emits toxic fumes under fire conditions. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. ENVIRONMENTAL PRECAUTION(S) Do not allow material to enter drains or water courses. Avoid contaminating sewers and waterways with this material. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Do not use if skin is cut or scratched. Wash thoroughly after handling. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, FLUKAwww.molbase.com sparks, and open flame. Store at -20°C 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Discard contaminated clothing and shoes. EXPOSURE LIMITS CountrySourceTypeValue PolandNDS100 MG/M3 PolandNDSCh300 MG/M3 PolandNDSP- EXPOSURE LIMITS - DENMARK SourceTypeValue OELTWA260,0000 mg/m3 200,0000 ppm Remarks: H, methanol EXPOSURE LIMITS - GERMANY SourceTypeValue TRGS 900OEL260,0000 mg/m3 200,0000 ppm Remarks: 4 Remarks: H, methanol EXPOSURE LIMITS - NORWAY SourceTypeValue OELTWA130,0000 mg/m3 100,0000 ppm Remarks: H, methanol EXPOSURE LIMITS - SWEDEN SourceTypeValue LLV (Level250,0000 mg/m3 200,0000 ppm Remarks: H Remarks: methanol EXPOSURE LIMITS - SWITZERLAND SourceTypeValue OEL OEL260,0000 mg/m3 200,0000 ppm Remarks: H M C Remarks: methanol EXPOSURE LIMITS - UNITED KINGDOM SourceTypeValue OEL OEL266,0000 mg/m3 200,0000 ppm Remarks: methanol OELSTEL333,0000 mg/m3 250,0000 ppm Remarks: Skin Indicative limit value FLUKAwww.molbase.com Remarks: methanol PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Use supplied-air or SCBA respirators. Europe permits the use of type AXBEK full-face cartridge respirators (EN 14387). Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties AppearancePhysical State: Liquid PropertyValueAt Temperature or Pressure pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash PointN/A FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Stable: Stable. Materials to Avoid: Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Alkali metals, Reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur 11 - Toxicological Information SIGNS AND SYMPTOMS OF EXPOSURE Nausea, headache, and vomiting. Gastrointestinal disturbances. Dizziness. Weakness. Confusion. Drowsiness. Unconsciousness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. FLUKAwww.molbase.com Ingestion can cause: Methyl alcohol may be fatal or cause blindness if swallowed. Cannot be made non-poisonous. ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN INFORMATION Eyes. Kidneys. Liver. Heart. 12 - Ecological Information No data available. 13 - Disposal Considerations SUBSTANCE DISPOSAL Contact a licensed professional waste disposal service to dispose of this material. Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR UN#: 1230 Class: 3 PG: II Subrisk: 6.1 Proper Shipping Name: Methanol solution IMDG UN#: 1230 Class: 3 PG: II Subrisk: 6.1 Proper Shipping Name: Methanol solution Marine Pollutant: No Severe Marine Pollutant: No IATA UN#: 1230 Class: 3 PG: II Subrisk: 6.1 Proper Shipping Name: Methanol solution Inhalation Packing Group I: No 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: F-T Highly Flammable. Toxic. R-PHRASES: 11-23/24/25-39/23/24/25 Highly flammable. Toxic by inhalation, in contact with skin and FLUKAwww.molbase.com if swallowed. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. S-PHRASES: 7-16-36/37-45 Keep container tightly closed. Keep away from sources of ignition - no smoking. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Caution: Substance not yet fully tested (EU). COUNTRY SPECIFIC INFORMATION Germany WGK: 1 Self-Classification 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. FLUKAwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A