1338-14-3

• 常用中文名：环烷酸铁
• 常用英文名：Iron naphthenate
• CAS号：1338-14-3
• 分子式：C₂₂H₁₄FeO₄
• 分子量：398.18900
• 相关类别： 有机原料 羧酸类化合物及衍生物 羧酸酯及其衍生物的盐
• 发布时间：2018-05-05 08:00:00
• 更新时间：2024-01-02 13:57:39
• 作为涂料用催干剂及重质燃料的助燃剂

名称

• 中文名: 萘烯酸铁
• 英文名: iron(2+),naphthalene-2-carboxylate
• 英文别名: MFCD00147295; FERRIC NAPHTHENATE; iron ion(2+) bis(2-naphthoate); Iron naphthenate; EINECS 215-660-7; naphthalene-2-carboxylate

物化性质

• 密度: 0,9 g/cm3
• 分子式: C₂₂H₁₄FeO₄
• 分子量: 398.18900
• 闪点: 40°C
• 精确质量: 398.02400
• PSA: 80.26000
• LogP: 2.40410
• 外观性状: 棕色液体
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物

• 水溶解性: Slightly soluble in water.
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:4

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积80.3

  7.重原子数量:27

  8.表面电荷:0

  9.复杂度:195

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1. 性状：棕色液体。

  2. 密度（g/mL,25/4℃）： 0.9

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）： 未确定

  7. 折射率： 未确定

  8. 闪点（ºC）： 40

  9. 比旋光度（º）： 未确定

  10. 自燃点或引燃温度（ºC）： 未确定

  11. 蒸气压（kPa,25ºC）： 未确定

  12. 饱和蒸气压（kPa,60ºC）： 未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）： 未确定

  15. 临界压力（KPa）： 未确定

  16. 油水（辛醇/水）分配系数的对数值： 未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）： 未确定

  19. 溶解性：不溶于水。

MSDS

Section 1: Product Identification Chemical Name:Iron naphthenate, 80% in mineral spirits (12% Fe) CAS Registry Number:1338-14-3 Formula:Fe salt of napthenic acid EINECS Number:none Chemical Family:metal carboxylate Synonym:Naphthenic acid, iron salt, in petroleum spirits, paraffin oil. Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound1338-14-380%no datano data mineral spirits64475-85-020%no datano data Section 3: Hazards Identification Emergency Overview:Liquid is irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes, inhalation, skin Eye Contact:Causes irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Vapor is irritating to the nose, mucous membranes and respiratory tract, and cause drowsiness. Ingestion:Ingestion may cause gastrointestinal distress, dizziness, weakness, and drowsiness. Irritating to skin, eyes and respiratory tract. Mineral spirits entering lungs during vomiting can cause severe Acute Health Affects: pulmonary injury. Chronic Health Affects:No data available NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Do not Ingestion: induce vomiting unless directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:>100 °F Autoignition Temperature:445 °F (mineral sp Explosion Limits:0.7-8.9% in air (mineral s Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable material. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable Spill and Leak Procedures: adsorbent, and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container and store in a cool place. Handle in a well ventilated area. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown liq. Molecular Weight:not applicable Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:organic odor Solubility in Water:slightly soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable liquid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Keep away from heat and ignition sources including open flame and electrostatic discharge. Incompatibility:Oxidizing agents Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information No information available in the RTECS files for title compound. For Mineral Spirits: Oral (rat); LD50:>34600 RTECS Data:mg/Kg; Inhalation (rat) LC50: >21400 mg/m3/4H; Intraperitoneal (rat) LDLo: 8560 mg/kg; Skin (rabbit) LD50: 15400 mg/kg. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):NA Packaging Group (CFR):III UN ID Number (CFR):UN# 1993 Shipping Name (IATA):Flammable liquid, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):NA Packaging Group (IATA):III UN ID Number (IATA):UN# 1993 SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:Listed in the TSCA inventory SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常来说对水是无害的，若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn
• 风险声明 (欧洲): R10
• 安全声明 (欧洲): S16-S26-S36/37/39
• 危险品运输编码: UN 1993
• 包装等级: III