10361-44-1
10361-44-1结构式
- 常用中文名：硝酸铋
- 常用英文名：Bismuth nitrate
- CAS号：10361-44-1
- 分子式：BiN3O9
- 分子量：394.995
- 相关类别： 无机化工 无机盐 金属硝酸盐及亚硝酸盐
- 发布时间：2018-06-23 18:33:41
- 更新时间：2024-01-05 19:49:26
-
用于药物和铋盐制造，用作各种触媒原料。
| 中文名 | 硝酸铋 |
|---|---|
| 英文名 | Bismuth nitrate |
| 中文别名 | 五水合硝酸铋(III) |
| 英文别名 |
Trinitric acid bismuth salt
BISMUTH (III) NITRATE EINECS 233-791-8 Bismuth(3+) trinitrate MFCD00003460 Nitricacid,bismuth(3+)salt bismuth nitrate Bismuth(III) nitrate Bismuthternitrate Bismuth(III) nitrate hydrate,Puratronic(R),99.9 (metals basis) Nitric acid bismuth salt Trinitric acid bismuth(III) salt |
| 密度 | 2.83 g/cm3 |
|---|---|
| 沸点 | 83ºC |
| 熔点 | 30ºC |
| 分子式 | BiN3O9 |
| 分子量 | 394.995 |
| 精确质量 | 394.943848 |
| PSA | 206.64000 |
| LogP | 0.85230 |
| 外观性状 | 透明,无色晶体 |
| 储存条件 | 储存注意事项 储存于阴凉、通风的库房。远离火种、热源。库温不超过30℃，相对湿度不超过80%。包装密封。应与易（可）燃物、还原剂等分开存放，切忌混储。储区应备有合适的材料收容泄漏物。 |
| 稳定性 | 1.稳定性 稳定 2.禁配物 还原剂、易燃或可燃物、活性金属粉末、硫、磷 3.避免接触的条件 潮湿空气 4.聚合危害 不聚合 5.分解产物 氮氧化物 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:9 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积189 7.重原子数量:13 8.表面电荷:0 9.复杂度:18.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:4 |
| 更多 | 1.性状：无色透明有光泽结晶，有吸湿性。 2.熔点（℃）：75~80（分解） 3.沸点（℃）：分解 4.相对密度（水=1）：2.83 5.溶解性：溶于稀硝酸、乙醇、丙酮。 |
Synonym:Nitric acid, bismuth (+3) salt Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/38 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes and skin. Contact with combustible material may cause fire.Corrosive.Hygroscopic. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and possible eye burns. Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe irritation and possible burns. Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Inhalation: May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Chronic: May cause reproductive and fetal effects. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately. Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Autoignition Temperature: Not applicable. Flash Point: Not applicable. NFPA Rating: Not published. Explosion Limits, Lower: Not available. Upper: Not available. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a cool, dry place. Keep container closed when not in use. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Appearance: white Odor: Pungent odor. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 30 deg C (decomposes) Decomposition Temperature: Not available. Solubility: Decomposed by water. Specific Gravity/Density: 2.83 Molecular Formula: BiN3O9 Molecular Weight: 394.9987 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, contact with water, combustible materials, heating to decomposition. Incompatibilities with Other Materials: Heat, cumbustible materials, and water. Hazardous Decomposition Products: Oxides of nitrogen, irritating and toxic fumes and gases, bismuth oxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10361-44-1: EB2984400 LD50/LC50: Not available. Carcinogenicity: Bismuth nitrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION For further information, contact Fisher Scientific. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION CDG/CPL Shipping Name: NITRATES, INORGANIC, NOS Hazard Class: 5.1 UN Number: 1477 Packing Group: II IMO No information available. IATA No information available. RID/ADR No information available. Canadian TDG No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI O Risk Phrases: R 36/38 Irritating to eyes and skin. R 8 Contact with combustible material may cause fire. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). WGK (Water Danger/Protection) CAS# 10361-44-1: Canada CAS# 10361-44-1 is listed on Canada's DSL/NDSL List. WHMIS: Not available. CAS# 10361-44-1 is not listed on Canada's Ingredient Disclosure List. Exposure Limits US FEDERAL TSCA CAS# 10361-44-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 1.急性毒性 LD50：4042mg/kg（大鼠经口）；3710mg/kg（小鼠经口） 2.刺激性 暂无资料 生态学数据: 1.生态毒性 暂无资料 2.生物降解性 暂无资料 3.非生物降解性 暂无资料 4.其他有害作用 该物质对环境有危害，应特别注意对水体的污染。 CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 危害码 (欧洲) | Xi |
|---|---|
| 危险品运输编码 | UN 1477 |
| 包装等级 | II |
| 危险类别 | 5.1 |
| 海关编码 | 2834299090 |
| 海关编码 | 2834299090 |
|---|