17243-13-9

• 常用中文名：5-氯磺酰基-2-羟基苯甲酸
• 常用英文名：5-Chlorosulfonyl-2-hydroxy-benzoic acid
• CAS号：17243-13-9
• 分子式：C₇H₅ClO₅S
• 分子量：236.630
• 发布时间：2018-03-23 08:00:00
• 更新时间：2024-01-08 12:44:36
• 下载msds

名称

• 中文名: 5-氯磺酰基-2-羟基苯甲酸
• 英文名: 5-(Chlorosulfonyl)-2-hydroxybenzoic acid
• 中文别名: 5-(磺酰氯)水杨酸
• 英文别名: 5-(Chlorosulfonyl)-2-hydroxybenzoic acid; 5-Chlorosulfonyl-2-hydroxy-benzoic acid; 5-chlorosulfonyl-2-hydroxybenzoic acid; Benzoic acid, 5-(chlorosulfonyl)-2-hydroxy-; MFCD00052974

物化性质

• 密度: 1.7±0.1 g/cm3
• 沸点: 434.6±40.0 °C at 760 mmHg
• 熔点: 171-174°C
• 分子式: C₇H₅ClO₅S
• 分子量: 236.630
• 闪点: 216.6±27.3 °C
• 精确质量: 235.954620
• PSA: 100.05000
• LogP: 2.70
• 蒸汽压: 0.0±1.1 mmHg at 25°C
• 折射率: 1.621
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 氧化物 碱
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:2

  3.氢键受体数量:5

  4.可旋转化学键数量:2

  5.互变异构体数量:4

  6.拓扑分子极性表面积100

  7.重原子数量:14

  8.表面电荷:0

  9.复杂度:320

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：不确定

  2. 密度（g/mL,25/4℃）：不确定

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：171-174

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC, 5.2kPa）：不确定

  7. 折射率：不确定

  8. 闪点（ºC）：不确定

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：不确定

MSDS

Name: 5-Chlorosulfonyl-2-hydroxybenzoic acid 97% Material Safety Data Sheet Synonym: CAS: 17243-13-9 Section 1 - Chemical Product MSDS Name:5-Chlorosulfonyl-2-hydroxybenzoic acid 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 17243-13-9 5-Chlorosulfonyl-2-hydroxybenzoic acid 97% unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Wash mouth out with water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 17243-13-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 171 - 174 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H5ClO5S Molecular Weight: 237 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, bases. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 17243-13-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 5-Chlorosulfonyl-2-hydroxybenzoic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 17243-13-9: 1 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 17243-13-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 17243-13-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): C:Corrosive;
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S26-S36/37/39
• 危险品运输编码: 3261
• 包装等级: III
• 危险类别: 8
• 海关编码: 2918290000

合成路线

69-72-7 ~63% 17243-13-9

文献：Obafemi, Craig. A.; Onigbinde, Adebayo O. Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 57, # 1/2 p. 75 - 81

97-05-2 ~% 17243-13-9

文献：Journal of the Chemical Society, , vol. 121, p. 2558

50-78-2 ~52% 17243-13-9

文献：Cremlyn, Richard; Swinbourne, Frederick; Atherall, John; Courtney, Lynn; Cronje, Theo; at al. Phosphorus and Sulfur and the Related Elements, 1980 , vol. 9, p. 155 - 164

135251-12-6 ~38% 17243-13-9

文献：Lowe; Braden Archiv der Pharmazie, 1995 , vol. 328, # 3 p. 283 - 285

54-21-7 ~% 17243-13-9

文献：Zhurnal Obshchei Khimii, , vol. 20, p. 1818,1823; engl. Ausg. S. 1883, 1888

7790-94-5 97-05-2 ~% 17243-13-9

文献：Journal of the Chemical Society, , vol. 121, p. 2558

上下游产品

上游产品  6
69-72-7 97-05-2 50-78-2 135251-12-6
54-21-7 7790-94-5
下游产品  10
24619-05-4 200575-15-1 139755-83-2 17645-94-2
68003-34-9 68029-77-6 91134-85-9 92200-76-5
62547-03-9 62547-13-1

海关

海关编码	2918290000
中文概述	2918290000 其他含酚基但不含其他含氧基羧酸及其酸酐、酰卤化物、过氧化物和过氧酸及它们的衍生物。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验
Summary	HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%