105994-55-6

105994-55-6结构式

常用中文名：4-溴-1-甲基-3-苯基-1H-吡唑
常用英文名：4-Bromo-1-methyl-3-phenyl-1H-pyrazole
CAS号：105994-55-6
分子式：C₁₀H₉BrN₂
分子量：237.096
发布时间：2018-12-04 12:06:55
更新时间：2024-01-09 16:47:11

中文名	1-甲基-3-苯基-1H-吡唑-4-羧酸
英文名	1-methyl-3-phenylpyrazole-4-carboxylic acid
英文别名	4-Bromo-1-methyl-3-phenyl-1H-pyrazole 1H-Pyrazole, 4-bromo-1-methyl-3-phenyl- 4-Brom-1-methyl-3-phenyl-1H-pyrazol 1H-Pyrazole,4-bromo-1-methyl-3-phenyl 1-METHYL-3-PHENYL-1H-PYRAZOLE-4-CARBOXYLIC ACID 4-bromo-3-phenyl-1-methylpyrazole MFCD28024785

密度	1.4±0.1 g/cm3
沸点	317.8±22.0 °C at 760 mmHg
熔点	101.6ºC
分子式	C₁₀H₉BrN₂
分子量	237.096
闪点	146.0±22.3 °C
精确质量	235.994904
PSA	17.82000
LogP	2.99
外观性状	固体或液体
蒸汽压	0.0±0.7 mmHg at 25°C
折射率	1.626
储存条件	室温，密封，干燥

Name:	4-Bromo-1-methyl-3-phenyl-1h-pyrazole 97% Material Safety Data Sheet
Synonym:
CAS:	105994-55-6

Section 1 - Chemical Product MSDS Name:4-Bromo-1-methyl-3-phenyl-1h-pyrazole 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
105994-55-6	4-Bromo-1-methyl-3-phenyl-1H-pyrazole	97%	unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 105994-55-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 101.6 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H9BrN2
Molecular Weight: 237.1

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 105994-55-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromo-1-methyl-3-phenyl-1H-pyrazole - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 105994-55-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 105994-55-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 105994-55-6 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

危害码 (欧洲)	Xi:Irritant;
风险声明 (欧洲)	R36/37/38
安全声明 (欧洲)	S26-S37/39
海关编码	2933199090

3463-26-1

~77%

105994-55-6

文献：Kano, Kunio; Scarpetti, David; Warner, John C.; Anselme, Jean-Pierre; Springer, James H.; Arison, Byron H. Canadian Journal of Chemistry, 1986 , vol. 64, p. 2211 - 2219

3506-51-2

105994-55-6

文献：v. Auwers; Schmidt Chemische Berichte, 1925 , vol. 58, p. 537

57623-20-8

105994-55-6

文献：v. Auwers; Schmidt Chemische Berichte, 1925 , vol. 58, p. 537

2458-26-6

105994-55-6

文献：v. Auwers; Schmidt Chemische Berichte, 1925 , vol. 58, p. 537

上游产品 3
3463-26-1 3506-51-2 2458-26-6
下游产品 0

海关编码	2933199090
中文概述	2933199090. 其他结构上有非稠合吡唑环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933199090. other compounds containing an unfused pyrazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1158522-08-7	940364-43-2
134104-43-1	131615-57-1
1251556-32-7	6906-52-1
930439-75-1	1018584-77-4
1375289-11-4	849349-65-1